1,2-bis(4,6-dimethoxy-1,3,5-triazin-2-yl)diazene | 1033125-78-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1,2-bis(4,6-dimethoxy-1,3,5-triazin-2-yl)diazene
• 英文别名: Bis-(4,6-dimethoxy-[1,3,5]triazin-2-yl)-diazene；bis(4,6-dimethoxy-1,3,5-triazin-2-yl)diazene
• CAS: 1033125-78-8
• 化学式: C₁₀H₁₂N₈O₄
• 分子量: 308.256
• InChiKey: JNVXTXUAAWBIEG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  139
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1,2-bis(4,6-dimethoxy-1,3,5-triazin-2-yl)diazene 在 一水合肼 作用下， 以 乙醇 为溶剂， 反应 4.0h， 以97%的产率得到N,N'-bis(4,6-dimethoxy-1,3,5-triazin-2-yl)hydrazine
  参考文献：
  名称：

  Azo bond hydrogenation with hydrazine, R–NHNH2, and hydrazobenzene

  摘要：

  Hydrogenation of azo bonds with hydrazine, mono-substituted hydrazine, and hydrazobenzene was studied with selected diazene compounds under oxygen-free conditions. The reactions proceed rapidly and in high yield in several solvents, utilizing all N-H protons. While the reduction process is accompanied by the evolution of nitrogen gas in the case of N(2)H(4), the intermediacy of diimide could not be confirmed by standard trapping experiments. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.03.083
• 作为产物：
  描述：

  N,N'-bis(4,6-dimethoxy-1,3,5-triazin-2-yl)hydrazine 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 乙腈 为溶剂， 反应 2.0h， 以77%的产率得到1,2-bis(4,6-dimethoxy-1,3,5-triazin-2-yl)diazene
  参考文献：
  名称：

  Azo bond hydrogenation with hydrazine, R–NHNH2, and hydrazobenzene

  摘要：

  Hydrogenation of azo bonds with hydrazine, mono-substituted hydrazine, and hydrazobenzene was studied with selected diazene compounds under oxygen-free conditions. The reactions proceed rapidly and in high yield in several solvents, utilizing all N-H protons. While the reduction process is accompanied by the evolution of nitrogen gas in the case of N(2)H(4), the intermediacy of diimide could not be confirmed by standard trapping experiments. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.03.083

文献信息

• High-energy 1,3,5-triazinyl diazenes, and process thereof
  申请人：The United States of America as represented by the Secretary of the Navy

  公开号：US07399841B1

  公开（公告）日：2008-07-15

  A compound possesses the chemical structure of: wherein n is greater than zero. The compound is useful in energetic composition, particularly in linear, branched, dendritric, oligomer and cyclic oligomer azo-triazine forms.

  这个化合物的化学结构为：其中n大于零。这个化合物在能量组分中很有用，特别是在线性、分支、树状、寡聚体和环状寡聚体偶氮三嗪形式中。