| 1071519-75-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 1071519-75-9
• 化学式: C₈H₁₉N₂*I
• 分子量: 270.157
• InChiKey: WGAKHRCDBKULDF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.27
• 重原子数：
  11.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  Propanal, 2,2-dimethyl, dimethylhydrazone 、 碘甲烷 反应 0.25h， 以1.00 g的产率得到
  参考文献：
  名称：

  腙和肟的水解稳定性。

  摘要：

  Hydrazones and oximes are common conjugates, but are labile to hydrolysis. The hydrolytic stability of isostructural hydrazones and an oxime have been determined at pD 5.0–9.0. The hydrolysis of each adduct was catalyzed by acid. Rate constants for oxime hydrolysis were nearly 103-fold lower than those for simple hydrazones; a trialkylhydrazonium ion (formed after condensation) was even more stable than the oxime. The data suggest a general mechanism for conjugate hydrolysis.

  DOI：

  10.1002/anie.200802651