dichloro bis(diethylamine) palladium (II) | 18955-12-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: dichloro bis(diethylamine) palladium (II)
• CAS: 18955-12-9；96093-21-9
• 化学式: C₈H₂₂Cl₂N₂Pd
• 分子量: 323.602
• InChiKey: IFUVSFMSBUWKBJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 二乙胺 以 乙腈 为溶剂， 以82%的产率得到dichloro bis(diethylamine) palladium (II)
  参考文献：
  名称：

  Reactions of the homoleptic acetonitrile complexes of palladium and platinum with diethylamine

  摘要：

  The homoleptic [M(MeCN)(4)](2+) cations (M = Pd, Pt) as the tetrafluoroborato derivatives were reacted with NHEt(2). The platinum species affords the amidino derivative {Pt[(E)-HN=C(NEt(2))Me](4)}[BF(4)](2), 1, as the only detected product of the addition of the amine to the coordinated nitrile. On the contrary, for [Pd(MeCN)(4)][BF(4)](2) competition between the substitution of the nitrile and addition of the amine to the nitrile group is operative: by carrying out the reaction in acetonitrile as solvent, complete conversion was obtained to the crystallographically defined {Pd[(E)-HN=C(NEt(2))Me](4)}[BF(4)](2). Consistent with these findings, PdCl(2)(MeCN)(2) reacts with NHEt(2) in acetonitrile yielding the substitution complex PdCl(2)(NHEt(2))(2), whereas the amidino complex cis-PtCl(2)[(E)-HN=C(NEt(2))Me](2), 3 was obtained from PtCl(2)(MeCN)(2). Complex 3 was characterized by X-ray diffractometry. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.04.001

文献信息

• Electronic Absorption, Magnetic Circular Dichroism, and Circular Dichroism Spectra of<i>cis</i>- and<i>trans</i>-[Pd(Cl)₂(N)₂]-type Complexes and Their Electronic Structures
  作者：Kazuhiko Nakayama、Takashi Komorita、Yoichi Shimura

  DOI：10.1246/bcsj.57.1336

  日期：1984.5

  , N,N-diethylethylenediamine, and N,N-dimethyl-1,3-propanediamine) and trans-[PdCl2(L)2] (L=EtNH2, Me2NH, Me3N, n-BuNH2, i-BuNH2, s-BuNH2, t-BuNH2, and rac-pea (pea=1-phenylethylamine)), and CD spectra of [PdCl2L] (L=(S)-1,2-propanediamine-(S-pn) and (2S)-N1,N1-diethyl-1,2-propanediamine) and trans-[PdCl2(S-pea)2] have been measured over the visible-near UV region, together with the corresponding spectra

  [PdCl2L] (L=乙二胺(en)、1,3-丙二胺、N,N-二甲基乙二胺、N,N'-二甲基乙二胺、N,N-二乙基乙二胺和N,N-二甲基- 1,3-丙二胺）和反式-[PdCl2(L)2]（L=EtNH2、Me2NH、Me3N、n-BuNH2、i-BuNH2、s-BuNH2、t-BuNH2 和 rac-pea（豌豆=1-苯乙胺））和 [PdCl2L]（L=(S)-1,2-丙二胺-(S-pn) 和 (2S)-N1,N1-二乙基-1,2-丙二胺）和反式-[ PdCl2(S-pea)2] 已在可见光-近紫外区域测量，以及 [PtCl2L] 的相应光谱（L=en 和 S-pn）。三种光谱的检查及其高斯分析表明顺式配合物的金属d轨道分裂模式与[PdCl4]2-类似，并且对于反式复合物，dx2−y2←dxz 和 dyz 跃迁在很大程度上分裂以给出明显的两个自旋允许的 dd 带特征的反式复合物。dx2−y2←dxz
• Anillo, Adela; Dell'Amico, Daniela Belli; Calderazzo, Fausto, Gazzetta Chimica Italiana, 1989, vol. 119, # 12, p. 653 - 656
  作者：Anillo, Adela、Dell'Amico, Daniela Belli、Calderazzo, Fausto、Pelizzi, Giancarlo、Rocchi, Lucia

  DOI：——

  日期：——
• Palladium-assisted amination of olefins. A mechanistic study
  作者：Louis S. Hegedus、Bjorn Akermark、Krister Zetterberg、Lars F. Olsson

  DOI：10.1021/ja00335a042

  日期：1984.11
• Dialkylcarbamato complexes of palladium(II). Crystal structure of trans-[Pd(O2CNEt2)2(NHEt2)2]
  作者：Adela Anillo、Daniela Belli Dell'Amico、Fausto Calderazzo、Mario Nardelli、Giancarlo Pelizzi、Lucia Rocchi

  DOI：10.1039/dt9910002845

  日期：——

  The reaction of [Pd(MeCN)4][BF4]2 with NHR2 (R = Et or Pr(i)) and carbon dioxide in toluene led to the dialkylcarbamato complexes [Pd(O2CNR2)2(NHR2)2]. The derivative trans-[Pd(O2CNEt2)2(NHEt2)2] was studied by X-ray diffraction methods. The square-planar geometry of the palladium atom involves one oxygen atom of each monodentate carbamato group and two amine nitrogen atoms. An intramolecular N-H ... O bond is probably responsible for a further stabilization within the molecule, for the features of the IR bands associated with the carbamato ligand and for the H-1 NMR non-equivalence observed within the amine alkyl group at room temperature.
• Gutbier, A.; Krell, A., Chemische Berichte, 1906, vol. 39, p. 1293 - 1293
  作者：Gutbier, A.、Krell, A.

  DOI：——

  日期：——