[(NC5H3(C(Me)NC6H4-t-Bu)2)Co(I)(η-ethylene)][AlMe3Cl] | 1192144-29-8

• 英文名称: [(NC5H3(C(Me)NC6H4-t-Bu)2)Co(I)(η-ethylene)][AlMe3Cl]
• CAS: 1192144-29-8
• 化学式: C₃H₉AlCl*C₃₁H₃₉CoN₃
• 分子量: 620.203
• InChiKey: LFGFTGBEUWVMBQ-CFKKOXEFSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,6-bis(1-(2-tert-butylphenylimino)ethyl)pyridine cobalt(II) chloride 、 乙烯 、 三甲基铝 以 氘代甲苯 为溶剂， 生成 [(NC5H3(C(Me)NC6H4-t-Bu)2)Co(I)(η-ethylene)][AlMe3Cl]
  参考文献：
  名称：

  Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts

  摘要：

  The activation of bis(imino)pyridine cobalt-based catalysts of ethylene polymerization with methylalumoxane (MAO), AlMe3, and AlMe3/[CPh3][B(C6F5)(4)] has been studied by H-1, H-2, and F-19 NMR and EPR spectroscopy. The nature of the active sites of polymerization is discussed. The polymerization kinetics and the polymer properties for the different catalyst/activator systems were correlated with spectroscopic data.

  DOI：

  10.1021/om900490b