{Pt(PMe₃)}₃(μ-Ge-nBu₂)₃ | 1609208-02-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: {Pt(PMe₃)}₃(μ-Ge-nBu₂)₃
• CAS: 1609208-02-7
• 化学式: C₃₃H₈₁Ge₃P₃Pt₃
• 分子量: 1373.94
• InChiKey: XEBREISYHWXYNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.45
• 重原子数：
  42.0
• 可旋转键数：
  21.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  四氟硼酸-二乙醚络合物 、 {Pt(PMe₃)}₃(μ-Ge-nBu₂)₃ 以 甲苯 为溶剂， 反应 0.5h， 生成 [{Pt(PMe₃)}₃(μ-GenBu₂)₃(μ₃-H)]*BF₄
  参考文献：
  名称：

  Cationic Hydridotriplatinum Complex with Bridging Germylene Ligands

  摘要：

  Triplatinum complexes with bridging secondary germylene ligands, [(Pt(PMe3)}(3)(mu-GeR2)(3)] (R = Ph, Bu-n), were prepared from the reaction of H2GeR2 with [Pt(PMe3)4] in a 1:1 ratio. Protonation of the triplatinum complexes with HBF4 led to formation of the cationic hydride complexes [{Pt(PMe3)}(3)(mu-GeR2)(3)(mu(3)-H)D3F4 (R = Ph, Bu-n). The results of multinuclear NMR spectra and DFT calculations of the cationic complexes revealed that the Pt3H core has a trigonal-pyramidal structure with rapid exchange of the mu(3)-hydride ligand position between the two possible positions on the opposite side of the Pt-3 plane.

  DOI：

  10.1021/om500309k
• 作为产物：
  描述：

  四(三甲基膦)铂(0) 、 dibutylgermane 以 甲苯 为溶剂， 反应 24.0h， 以47%的产率得到{Pt(PMe₃)}₃(μ-Ge-nBu₂)₃
  参考文献：
  名称：

  Cationic Hydridotriplatinum Complex with Bridging Germylene Ligands

  摘要：

  Triplatinum complexes with bridging secondary germylene ligands, [(Pt(PMe3)}(3)(mu-GeR2)(3)] (R = Ph, Bu-n), were prepared from the reaction of H2GeR2 with [Pt(PMe3)4] in a 1:1 ratio. Protonation of the triplatinum complexes with HBF4 led to formation of the cationic hydride complexes [{Pt(PMe3)}(3)(mu-GeR2)(3)(mu(3)-H)D3F4 (R = Ph, Bu-n). The results of multinuclear NMR spectra and DFT calculations of the cationic complexes revealed that the Pt3H core has a trigonal-pyramidal structure with rapid exchange of the mu(3)-hydride ligand position between the two possible positions on the opposite side of the Pt-3 plane.

  DOI：

  10.1021/om500309k