(3-chloro-phenyl)-(4-methoxy-phenyl)-diazene | 77350-55-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: (3-chloro-phenyl)-(4-methoxy-phenyl)-diazene
• 英文别名: (3-Chlor-benzol)-(1azo4)-phenol-methylaether；(3-Chlor-phenyl)-(4-methoxy-phenyl)-diazen；(3-Chlor-benzol)-(1azo4)-anisol；3'-Chlor-4-methoxy-azobenzol
• CAS: 77350-55-1
• 化学式: C₁₃H₁₁ClN₂O
• 分子量: 246.696
• InChiKey: LUKQUCARWBTZDV-FOCLMDBBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.76
• 重原子数：
  17.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  33.95
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  双乙烯酮 、 (3-chloro-phenyl)-(4-methoxy-phenyl)-diazene 以28%的产率得到
  参考文献：
  名称：

  KATO T.; SATO M.; TABEI K., J. ORG. CHEM. , 1974, 39, NO 22, 3205-3210

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 生成 (3-chloro-phenyl)-(4-methoxy-phenyl)-diazene
  参考文献：
  名称：

  Two textile townships, c. 1660-1820: a comparative demographic analysis

  摘要：

  Family reconstitution results for two industrializing townships in West Yorkshire are compared with findings from Cambridge Group reconstitutions and from similar European studies. The research highlights the variety of demographic experience between and within communities which experienced similar structural, economic, and technological shifts. This suggests that the construction of typologies of demographic change based on dominant occupations or sectors may be misleading, as may the assumption that economic transformation acted uniformly upon local populations. Aggregate shifts in demographic indicators in the townships appear to have been driven by significant change in the experience of relatively small, identifiable subgroups and cohorts. Rural industry seems to have stabilized communities, as well as changing them, and localized practices, culture, and responses conditioned and particularized economic change itself.

  DOI：

  10.1111/1468-0289.00175

文献信息

• Aryliminodimagnesium Reagents. IV. The Independent Preparation of Unsymmetrically Substituted Azoxyarene Isomers and Their Deoxygenation
  作者：Masao Okubo、K\={o}ji Koga

  DOI：10.1246/bcsj.56.203

  日期：1983.1

  By use of the condensation reaction of aryliminodimagnesium reagents (ArN(MgBr)2) with nitroarenes, six symmetrical and eight unsymmetrical azoxyarenes including four pairs of isomers were prepared in 40–80% yields. The deoxygenation reaction of the azoxyarenes by treating with five molar equivalents of p-MeOC6H4N(MgBr)2 at 55 °C in tetrahydrofuran was also studied, and the reactivity of deoxygenation

  通过使用芳基氨基二镁试剂 (ArN(MgBr)2) 与硝基芳烃的缩合反应，以 40-80% 的产率制备了包括四对异构体在内的六个对称和八个不对称氧化偶氮芳烃。还研究了在 55 °C 下在四氢呋喃中用 5 摩尔当量的 p-MeOC6H4N(MgBr)2 处理氧化偶氮芳烃的脱氧反应，脱氧反应的反应性与氧化偶氮芳烃的电子吸收最大值的移动相关。
• OKUBO, MASAO;KOGA, KOJI, BULL. CHEM. SOC. JAP., 1983, 56, N 1, 203-207
  作者：OKUBO, MASAO、KOGA, KOJI

  DOI：——

  日期：——