bis(N,N-di-iso-propyldithiocarbamato-S,S')platinum(II) | 71391-51-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis(N,N-di-iso-propyldithiocarbamato-S,S')platinum(II)
• 英文别名: N,N-di(propan-2-yl)carbamodithioate;platinum(2+)
• CAS: 71391-51-0
• 化学式: C₁₄H₂₈N₂PtS₄
• 分子量: 547.734
• InChiKey: IFVGVIKDAIKTCX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.17
• 重原子数：
  21.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  difluorophosphine sulfide 、 bis(N,N-di-iso-propyldithiocarbamato-S,S')platinum(II) 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Anderson, David M.; Ebsworth, E. A. V.; Stephenson, T. Anthony, Angewandte Chemie, 1981, vol. 93, p. 289 - 290

  摘要：

  DOI：
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 sodium N,N'-diisopropyldithiocarbamate 以 水 为溶剂， 以83%的产率得到bis(N,N-di-iso-propyldithiocarbamato-S,S')platinum(II)
  参考文献：
  名称：

  Dialkyldithiocarbamate platinum(II) complexes of [Pt(S2CNR2)2] (R = iso-C3H7, iso-C4H9): Preparation, 13C CP-MAS NMR, molecular structure, supramolecular self-assembly and thermal behaviour

  摘要：

  Two new dialkyldithiocarbamato platinum(II) complexes of [Pt(S2CNR)(2)], R = iso-C3H7 (1) and iso-C4H9 (2), have been prepared and characterised using C-13 CP-MAS NMR. The crystal and molecular structures of the isolated compounds were established by single-crystal X-ray diffraction. The unit cell of 1 contains four centrosymmetric discrete molecules of [Pt{S2CN(iso-C3H7)(2)}(2)], of which the pairs are structurally inequivalent to each other (hereafter denoted as molecules 1a and 1b). At the supramolecular level, due to numerous intermolecular C-H center dot center dot center dot S hydrogen bonds, the la molecules form linear polymeric ribbons, whose interaction with the 1b molecules results in a two-dimensional polymeric network. In the structure of 2, the construction of supramolecular zigzag chains by non-centrosymmetric molecules of [Pt{S2CN(iso-C4H9)(2)}(2)] is determined by intermolecular C-H center dot center dot center dot Pt anagostic interactions. The thermal behaviour of crystalline compounds 1 and 2 was studied by simultaneous thermal analysis (STA), a combination of the TG and DSC techniques, under an argon atmosphere. In both cases, platinum(II) sulfide (PtS) was identified as the main end-product upon thermal decomposition of the complexes at 600 degrees C. (C) 2019 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2019.114166

文献信息

• Anderson, David M.; Ebsworth, E. A. V.; Stephenson, T. Anthony, Journal of the Chemical Society, Dalton Transactions, 1982, p. 2343 - 2352
  作者：Anderson, David M.、Ebsworth, E. A. V.、Stephenson, T. Anthony、Walkinshaw, Malcolm D.

  DOI：——

  日期：——