N'-[chloro(dimethyl)germyl]-N'-[3-(dimethylamino)propyl]-N,N-dimethylpropane-1,3-diamine | 705290-23-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: N'-[chloro(dimethyl)germyl]-N'-[3-(dimethylamino)propyl]-N,N-dimethylpropane-1,3-diamine
• CAS: 705290-23-9
• 化学式: C₁₂H₃₀ClGeN₃
• 分子量: 324.433
• InChiKey: HCGBZGLLVKXBGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.13
• 重原子数：
  17.0
• 可旋转键数：
  9.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.72
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  3,3′-亚氨基双(N,N-二甲基丙胺) 、 二氯二甲基锗 在 三乙胺 作用下， 以 not given 为溶剂， 生成 N'-[chloro(dimethyl)germyl]-N'-[3-(dimethylamino)propyl]-N,N-dimethylpropane-1,3-diamine
  参考文献：
  名称：

  Properties and Reactions of Organosilanes and Organogermanes Containing the Potentially Bidentate (X(CH₂)_n)₂N‐Group

  摘要：

  Compounds in the series R3SiN[(CH2)(n)X](2) (R = (CH3)(2)H, (CH3)(2)Cl, and CH3ClH), R2Si[N((CH2)(n)X)(2)](2) (R = (CH3)(2), C6H5H, and C6H5Cl), R3GeN(CH2X)(2) (R = (CH3)(2)Cl and (C6H5)(2)Cl), and Cl2Sn[N-((CH2)(3)X)(2)](2), for X = N(CH3)(2), n = 3; and OCH3, n = 2, have been prepared and characterized by H-1, C-13 and Si-29 NMR spectroscopy, and by elemental analyses. For all the compounds studied, the terminal N(CH3)(2) and OCH3 groups appear not to coordinate to the central atom. The product C6H5Si{N[(CH2)(2)OCH3](2)}(2)B[3,5-(CF3)(2)C6H3](4), obtained from a reaction between C6H5HSi{N[(CH2)(2)OCH3](2)}(2) and (C6H5)(3)CB[3,5(CF3)(2)C6H3](4), should contain a silylium ion, but because of the suspected presence of a small quantity of silyl radical, has thus far eluded definitive characterization.

  DOI：

  10.1081/sim-120026551