bis(thiourea)nickel chloride | 18906-80-4

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: bis(thiourea)nickel chloride
• 英文别名: {NiCl2(thiourea)2}；nickel(2+);thiourea;dichloride
• CAS: 18906-80-4
• 化学式: C₂H₈Cl₂N₄NiS₂
• 分子量: 281.84
• InChiKey: IVKKSJOEORPJHD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -7.62
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  168
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  硫脲 、 nickel dichloride 以 水 为溶剂， 生成 bis(thiourea)nickel chloride
  参考文献：
  名称：

  Growth, spectral, optical and thermal characterization of new metallorganic crystal—Bisthiourea nickel chloride

  摘要：

  The novel nonlinear optical single crystal of bisthiourea nickel chloride (BTNC) was grown successfully by slow evaporation technique using water as solvent. The lattice parameters of the grown crystal have been determined by X-ray diffraction studies. Vibrational spectra were recorded to determine the symmetries of molecular vibrations. Presence of various functional groups of BTNC was identified through FTIR and Raman spectroscopic analyses. Optical absorbance spectrum recorded in the wavelength range of UV-vis-NIR revealed that this crystal has good optical transparency in the range 200-2000 nm. The second harmonic generation test of BTNC revealed the nonlinear nature of the crystal. The BTNC crystal was analyzed by differential thermal and thermo gravimetric analysis (DTA-TCA) to obtain its thermal stability. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2009.07.007