bis(trimethylsilyl)azanide;2-methyl-2-(oxidomethyl)propane-1,3-diolate;tin(2+) | 369362-45-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: bis(trimethylsilyl)azanide;2-methyl-2-(oxidomethyl)propane-1,3-diolate;tin(2+)
• CAS: 369362-45-8
• 化学式: C₂₂H₅₄N₂O₆Si₄Sn₄
• 分子量: 1029.86
• InChiKey: RTYVROINBMNZMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.32
• 重原子数：
  38
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  140
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  新戊醇 、 bis(trimethylsilyl)azanide;2-methyl-2-(oxidomethyl)propane-1,3-diolate;tin(2+) 以 not given 为溶剂， 生成 [(μ-tris(oxymethyl)ethane)Sn2(μ-neopentyloxy)]2
  参考文献：
  名称：

  Chemistry of a Novel Family of Tridentate Alkoxy Tin(II) Clusters

  摘要：

  The chemical interconversions observed for a novel family of trihydroxymethyl ethane (THME-H-3) ligated Sn(II) compounds have been determined using single-crystal X-ray and Sn-119 NMR experiments. (mu-THME)(2)Sn-3 (1) was isolated from the reaction of 3 equiv of [Sn(NR2)(2)](2) (R = SiMe3) with 4 equiv of THME as a unique trinuclear species capped above and below the plane of Sri atoms by two THME ligands. Upon reaction with "Sn(NR2)(2)", compound 1 rearranged to yield another novel molecule [(mu-THME)Sn2-(NR2)](2) (2). Compound 2 could also be formed directly from the stoichiometric mixture of THME-H-3 and [Sn(NR2)(2)](2). Further studies revealed that I would also rearrange in the presence of Sn(OR)(2) to form [(mu-THME)Sn-2(mu-OR)](2) [OR = OMe (3), OCH2Me (4), OCH2CH(Me)CH2CH3 (5), OCH2CMe3 (6, ONep), OC6H5 (7, not structurally characterized), OC6H4Me-3 (8), OC6H4Me-2 (9), OC6H3(Me)(2)-2,6 (10), OC6H3(CHMe2)(2)-2,6 (11). Additionally, 3-11 could by synthesized from the reaction of 2 and the appropriate H-OR. Sn-119 solution NMR studies of 2-11, in THF-d(8) indicate that an equilibrium between the parent complex and its disassociation products (1 and the free parent Sn alkoxy or amide precursor) exists at room temperature. This is a likely reason behind the ease of interconversion observed for 1. The generality of this exchange was further verified through the reaction of 1 with [Ti(mu-ONep)(ONeP)(3)](2), which led to the isolation of (mu- ONeP)(2)Sn-3(mu-THME)(2)Ti(ONeP)(2) (12). For 12, the solid-state structure was maintained in solution with no indication of an equilibrium.

  DOI：

  10.1021/ja0202309
• 作为产物：
  描述：

  1,1,1-三(羟甲基)乙烷 、 以 四氢呋喃 为溶剂， 以22%的产率得到bis(trimethylsilyl)azanide;2-methyl-2-(oxidomethyl)propane-1,3-diolate;tin(2+)
  参考文献：
  名称：

  Chemistry of a Novel Family of Tridentate Alkoxy Tin(II) Clusters

  摘要：

  The chemical interconversions observed for a novel family of trihydroxymethyl ethane (THME-H-3) ligated Sn(II) compounds have been determined using single-crystal X-ray and Sn-119 NMR experiments. (mu-THME)(2)Sn-3 (1) was isolated from the reaction of 3 equiv of [Sn(NR2)(2)](2) (R = SiMe3) with 4 equiv of THME as a unique trinuclear species capped above and below the plane of Sri atoms by two THME ligands. Upon reaction with "Sn(NR2)(2)", compound 1 rearranged to yield another novel molecule [(mu-THME)Sn2-(NR2)](2) (2). Compound 2 could also be formed directly from the stoichiometric mixture of THME-H-3 and [Sn(NR2)(2)](2). Further studies revealed that I would also rearrange in the presence of Sn(OR)(2) to form [(mu-THME)Sn-2(mu-OR)](2) [OR = OMe (3), OCH2Me (4), OCH2CH(Me)CH2CH3 (5), OCH2CMe3 (6, ONep), OC6H5 (7, not structurally characterized), OC6H4Me-3 (8), OC6H4Me-2 (9), OC6H3(Me)(2)-2,6 (10), OC6H3(CHMe2)(2)-2,6 (11). Additionally, 3-11 could by synthesized from the reaction of 2 and the appropriate H-OR. Sn-119 solution NMR studies of 2-11, in THF-d(8) indicate that an equilibrium between the parent complex and its disassociation products (1 and the free parent Sn alkoxy or amide precursor) exists at room temperature. This is a likely reason behind the ease of interconversion observed for 1. The generality of this exchange was further verified through the reaction of 1 with [Ti(mu-ONep)(ONeP)(3)](2), which led to the isolation of (mu- ONeP)(2)Sn-3(mu-THME)(2)Ti(ONeP)(2) (12). For 12, the solid-state structure was maintained in solution with no indication of an equilibrium.

  DOI：

  10.1021/ja0202309