Dimethyl-di(pyrazol-1-yl)silane | 301526-76-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Dimethyl-di(pyrazol-1-yl)silane
• CAS: 301526-76-1
• 化学式: C₈H₁₂N₄Si
• 分子量: 192.296
• InChiKey: CHEBADOGCTYIQK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.18
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  35.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Dimethyl-di(pyrazol-1-yl)silane 、 zinc(II) chloride 以 四氢呋喃 为溶剂， 以67%的产率得到(bis(pyrazolyl)dimethylsilane)ZnCl2
  参考文献：
  名称：

  Zinc bis(pyrazolyl)silane complexes

  摘要：

  The first two members of a new family of nitrogen-donor ligands, the bis(pyrazolyl)silanes Me2Si(3,5-R(2)pz)(2) (R = I-I, Me), have been readily synthesized in almost quantitative yield from Me2SiCl2 and the alkali metal pyrazolates M(3,5-R(2)pz) (M = Li or Na). Both bidentate ligands, abbreviated Bps and Bps(Me2), respectively, have been used to prepare the zinc derivatives LZnX2 (L = Bps, Bps(Me2); X = Cl, Br, I), all of which have been characterized by a combination of analytical and spectroscopic techniques and, in the case of (Bps(Me2))ZnI2, also by single-crystal X-ray diffraction. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00470-8

文献信息

• Zinc bis(pyrazolyl)silane complexes
  作者：Lauakia M. Richburg、Jamshaid A. Farouq、Christopher D. Incarvito、Arnold L. Rheingold*、Daniel Rabinovich*

  DOI：10.1016/s0277-5387(00)00470-8

  日期：2000.7

  The first two members of a new family of nitrogen-donor ligands, the bis(pyrazolyl)silanes Me2Si(3,5-R(2)pz)(2) (R = I-I, Me), have been readily synthesized in almost quantitative yield from Me2SiCl2 and the alkali metal pyrazolates M(3,5-R(2)pz) (M = Li or Na). Both bidentate ligands, abbreviated Bps and Bps(Me2), respectively, have been used to prepare the zinc derivatives LZnX2 (L = Bps, Bps(Me2); X = Cl, Br, I), all of which have been characterized by a combination of analytical and spectroscopic techniques and, in the case of (Bps(Me2))ZnI2, also by single-crystal X-ray diffraction. (C) 2000 Elsevier Science Ltd. All rights reserved.