2-chloro-n-butyl-1,3-dithia-2-stanna-cyclopentane | 136561-12-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 2-chloro-n-butyl-1,3-dithia-2-stanna-cyclopentane
• 英文别名: 2-butyl-2-chloro-1,3,2-dithiastannolane
• CAS: 136561-12-1
• 化学式: C₆H₁₃ClS₂Sn
• 分子量: 303.464
• InChiKey: LYPRQRCCNWPBAJ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  3.44
• 重原子数：
  10.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  1,10-菲罗啉 、 2-chloro-n-butyl-1,3-dithia-2-stanna-cyclopentane 以 二氯甲烷 为溶剂， 生成 2-chloro-2-n-butyl-1,3,-dithia-2-{1,10-phenanthroline}stannacyclopentane
  参考文献：
  名称：

  Synthesis of 2-chloro-2-n-butyl-1,3-dithia-2-stannacyclopentane and the crystal structure of its 1,10-phenanthroline complex

  摘要：

  2-Chloro-2-n-butyl-1,3-dithia-2-stannacyclopentane has been prepared and the structure of its 1,10-phenanthroline complex, C18H21ClN2S2Sn, has been determined by an X-ray diffraction study. The geometrical parameters indicate a distorted octahedral structure about the tin atom. The chlorine atom is trans to one nitrogen of the ligand in axial position, and the sulphur atoms, the carbon bonded to the tin and the other nitrogen form the equatorial plane. The SnS2C2 ring adopts an envelope form. No intermolecular contacts are observed.

  DOI：

  10.1016/0022-328x(91)86009-f
• 作为产物：
  描述：

  丁基三氯化锡 、 1,2-乙二硫醇 在 NaOH 作用下， 以 水 为溶剂， 以66%的产率得到2-chloro-n-butyl-1,3-dithia-2-stanna-cyclopentane
  参考文献：
  名称：

  Synthesis of 2-chloro-2-n-butyl-1,3-dithia-2-stannacyclopentane and the crystal structure of its 1,10-phenanthroline complex

  摘要：

  2-Chloro-2-n-butyl-1,3-dithia-2-stannacyclopentane has been prepared and the structure of its 1,10-phenanthroline complex, C18H21ClN2S2Sn, has been determined by an X-ray diffraction study. The geometrical parameters indicate a distorted octahedral structure about the tin atom. The chlorine atom is trans to one nitrogen of the ligand in axial position, and the sulphur atoms, the carbon bonded to the tin and the other nitrogen form the equatorial plane. The SnS2C2 ring adopts an envelope form. No intermolecular contacts are observed.

  DOI：

  10.1016/0022-328x(91)86009-f

文献信息

• BANDOLI, G.;CASELLATO, U.;PERUZZO, V.;PLAZZOGNA, G., J. ORGANOMET. CHEM., 411,(1991) N-2, C. 99-105
  作者：BANDOLI, G.、CASELLATO, U.、PERUZZO, V.、PLAZZOGNA, G.

  DOI：——

  日期：——