Sodium;tris(trimethylsilyl)silylformate | 1047654-85-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Sodium;tris(trimethylsilyl)silylformate
• CAS: 1047654-85-2
• 化学式: C₁₀H₂₇O₂Si₄*Na
• 分子量: 314.655
• InChiKey: QCDWXURGFKCGPG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.39
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME) 、 Sodium;tris(trimethylsilyl)silylformate 以 四氢呋喃 为溶剂， 以72%的产率得到Mo(2,6-diisopropylphenylimido)(CHCMe2Ph)(O2CSi(SiMe3)3)2
  参考文献：
  名称：

  Carboxylate-Based Molybdenum Alkylidene Catalysts: Synthesis, Characterization, and Use as Initiators for 1,6-Heptadiyne Cyclopolymerizations

  摘要：

  The carboxylate species Mo(NR)(CHCMe2R')(O2CCPh3)2 (R = various aryl groups or 1-adamantyl; R' = Ph or Me) have been synthesized by salt metathesis between Mo(NR)(CHCMe2R')(OTf)2(DME) (OTf = trifluoromethanesulfonate; DME = 1,2-dimethoxyethane) and sodium triphenylacetate. Other carboxylate compounds that have been prepared by this route include Mo(NAr)(CHCMe2Ph)(O2CR")2 (Ar = 2,6-i-Pr2C6H3; R" = CPh2Me, Si(SiMe3)3) and Na[Mo(NAd)(CHCMe2Ph)(02CAr')31 (Ar' = 2,6Me2C6H3). Terpheny1carboxylate species Mo(NR)(CHCMe2Ph)(02CTer)2 (Ter = 2,6-diphenyl-4-methylphenyl or 2,6-diphenyl-4-methoxyphenyl) were prepared through protonolysis of Mo(NR)(CHCMe2R')(Me2Pyr)2 with TerC02H, and one of them was characterized through X-ray crystallography. Trimethylphosphine adducts of selected triphenylacetate complexes have been isolated, and the X-ray crystal structure of Mo(NAr")(CH-t-BU)(02CCPh3)2(PMe3) (Ar" = 2-t-BUC61-14) was obtained. Several of the triphenylacetate complexes are active initiators for the regioselective polymerization of diethyl dipropargy1malonate (DEPDM).

  DOI：

  10.1021/om800314y