trimethylgermanate(II) | 54747-96-5

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: trimethylgermanate(II)
• CAS: 54747-96-5
• 化学式: C₃H₉Ge
• 分子量: 117.694
• InChiKey: JMAAQYYKDLNPMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲硫醇 、 trimethylgermanate(II) 生成 三甲基锗烷
  参考文献：
  名称：

  Electron Affinities and Gas-Phase Acidities of Organogermanium and Organotin Compounds

  摘要：

  The electron affinities have been measured for trimethylgermanium and trimethyltin radicals as 31.9 +/- 0.7 and 39.2 +/- 1.5 kcal/mol, respectively, using electron photodetachment spectroscopy. The acidities (Delta H degrees(acid)) for the corresponding hydrides (Me(3)GeH and Me(3)SnH) have been bracketed as 361.5 +/- 2.8 and 349 +/- 2 kcal/mol. From the electron affinities and the acidities, the D degrees(Me(3)MH) are derived as 79.8 +/- 3.5 and 75 +/- 3.5 kcal/mol, respectively. These physical properties are compared with the properties of the group IVA through group VIIA binary hydrides and methyl-substituted compounds. The electron affinities of the group IVA compounds do not conform to the regular pattern; some of the reasons for this are discussed.

  DOI：

  10.1021/ja00122a022
• 作为产物：
  描述：

  Hexamethyldigermane 、 氢氟酸 生成 氟-三甲基-锗烷 、 trimethylgermanate(II)
  参考文献：
  名称：

  Electron Affinities and Gas-Phase Acidities of Organogermanium and Organotin Compounds

  摘要：

  The electron affinities have been measured for trimethylgermanium and trimethyltin radicals as 31.9 +/- 0.7 and 39.2 +/- 1.5 kcal/mol, respectively, using electron photodetachment spectroscopy. The acidities (Delta H degrees(acid)) for the corresponding hydrides (Me(3)GeH and Me(3)SnH) have been bracketed as 361.5 +/- 2.8 and 349 +/- 2 kcal/mol. From the electron affinities and the acidities, the D degrees(Me(3)MH) are derived as 79.8 +/- 3.5 and 75 +/- 3.5 kcal/mol, respectively. These physical properties are compared with the properties of the group IVA through group VIIA binary hydrides and methyl-substituted compounds. The electron affinities of the group IVA compounds do not conform to the regular pattern; some of the reasons for this are discussed.

  DOI：

  10.1021/ja00122a022