1-(Dimethylphenylsilyloxy)-2-methylbutane | 176089-36-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1-(Dimethylphenylsilyloxy)-2-methylbutane
• 英文别名: dimethyl-(2-methylbutoxy)-phenylsilane
• CAS: 176089-36-4
• 化学式: C₁₃H₂₂OSi
• 分子量: 222.403
• InChiKey: NQOCHDPLLAOUJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.16
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-甲基丁醇 、 二甲基苯基硅烷 在 rhodium complex with caged, compact 4-(10-mercaptodecyl)-1-phospha-4-silabicyclo[2.2.2]octane on gold surface 作用下， 以 正己烷 为溶剂， 反应 16.0h， 以16%的产率得到1-(Dimethylphenylsilyloxy)-2-methylbutane
  参考文献：
  名称：

  具有链烷硫醇侧基的紧密膦的自组装单层：在Rh催化中具有显着的可重用性和底物选择性。

  摘要：

  DOI：

  10.1002/anie.200800884

文献信息

• Process for preparing alkylsilyl or arylsilyl ethers
  申请人：FMC Corporation

  公开号：US05493044A1

  公开（公告）日：1996-02-20

  A process for preparing alkylsilyl and arylsilyl ethers of the formula (R--O--SiR.sup.1 R.sup.2 R.sup.3) wherein R, R1, R2 and R3 are independently selected from the group consisting of hydrogen, alkyl groups containing one to twenty carbon atoms, substituted alkyl groups containing one to twenty carbon atoms, aryl groups containing six to eighteen carbon atoms, substituted aryl groups containing six to eighteen carbon atoms, hetero aryl groups containing four to eighteen carbon atoms, and substituted hetero aryl groups containing four to eighteen carbon atoms, with the proviso that R is never hydrogen, by reacting, in a hydrocarbon solvent, a chlorosilane of the formula R.sup.1 R.sup.2 R.sup.3 Si--Cl wherein R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl groups containing one to twenty carbon atoms, substituted alkyl groups containing one to twenty carbon atoms and aryl groups containing six to eighteen carbon atoms, substituted aryl groups containing six to eighteen carbon atoms, hetero aryl groups containing four to eighteen carbon atoms, and substituted hetero aryl groups containing four to eighteen carbon atoms with an alcohol of the formula ROH wherein R is an alkyl group containing one to twenty carbon atoms, a substituted alkyl group containing one to twenty carbon atoms, an aryl or substituted aryl group containing six to eighteen carbon atoms, or a hetero aryl or substituted hetero aryl group containing four to eighteen carbon atoms, in the presence of an organic acid acceptor (base) in a hydrocarbon solvent.

  一种制备(R--O--SiR.sup.1 R.sup.2 R.sup.3)的烷基硅醚和芳基硅醚的方法，其中R、R1、R2和R3独立地选择自氢、含有一到二十个碳原子的烷基、含有一到二十个碳原子的取代烷基、含有六到十八个碳原子的芳基、含有六到十八个碳原子的取代芳基、含有四到十八个碳原子的杂芳基和含有四到十八个碳原子的取代杂芳基的群体，但R永远不是氢，通过在烃溶剂中反应公式为R.sup.1 R.sup.2 R.sup.3 Si-Cl的氯硅烷和公式为ROH的醇，其中R是含有一到二十个碳原子的烷基、含有一到二十个碳原子的取代烷基、含有六到十八个碳原子的芳基或取代芳基、或含有四到十八个碳原子的杂芳基或取代杂芳基，在有机酸受体（碱）的存在下，在烃溶剂中进行。