The synthesis and characterization by infrared and raman spectroscopy of some ammine, methylamine, di- and tri-methylamine and aniline complexes of group VB (As, Sb and Bi) trihalides
作者:A.K. Biswas、J.R. Hall、D.P. Schweinsberg
DOI:10.1016/s0020-1693(00)91190-3
日期:1983.1
The preparation of ammines of formula MX3·NH3 (where M = As, Sb and Bi; X = Br and I) and SbCl3· 2NH3 are described. 1:1 complexes of mono-, di, trimethylamine and aniline with some antimony and bismuth trihalides have also been isolated. Infrared and Raman spectra are reported for the compounds in the solid state and the spectra are interpreted to indicate that the complexes are mononuclear. The configuration