2,6-dibenzhydryl-N-(2-(2,6-diethylphenylimino)acenaphthylenylidene)-4-methylbenzenamine | 1285664-39-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 2,6-dibenzhydryl-N-(2-(2,6-diethylphenylimino)acenaphthylenylidene)-4-methylbenzenamine
• 英文别名: 2-N-(2,6-dibenzhydryl-4-methylphenyl)-1-N-(2,6-diethylphenyl)acenaphthylene-1,2-diimine
• CAS: 1285664-39-2
• 化学式: C₅₅H₄₆N₂
• 分子量: 734.984
• InChiKey: RSULTXSOWXRLKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.6
• 重原子数：
  57
• 可旋转键数：
  10
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  乙二醇二甲醚溴化镍 、 2,6-dibenzhydryl-N-(2-(2,6-diethylphenylimino)acenaphthylenylidene)-4-methylbenzenamine 以 二氯甲烷 为溶剂， 以86.8%的产率得到[(2,6-dibenzhydryl-N-(2-(2,6-diethylphenylimino)acenaphthylenylidene)-4-methylbenzenamine)NiBr2]
  参考文献：
  名称：

  2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization

  摘要：

  A series of 2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamines (L1-L5) and the nickel(II) dibromide complexes thereof (C1-C5) were synthesized and. fully characterized. The molecular structures of representative complexes were determined by single-crystal X-ray diffraction and revealed a distorted-pyramidal geometry at nickel. All nickel(II) pro catalysts exhibited very high activity for the polymerization of ethylene, with activities as high as the range of 10(7) g of PE (mol of Ni)(-1) h(-1)

  DOI：

  10.1021/om200154a
• 作为产物：
  描述：

  苊醌 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 反应 16.0h， 生成 2,6-dibenzhydryl-N-(2-(2,6-diethylphenylimino)acenaphthylenylidene)-4-methylbenzenamine
  参考文献：
  名称：

  2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization

  摘要：

  A series of 2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamines (L1-L5) and the nickel(II) dibromide complexes thereof (C1-C5) were synthesized and. fully characterized. The molecular structures of representative complexes were determined by single-crystal X-ray diffraction and revealed a distorted-pyramidal geometry at nickel. All nickel(II) pro catalysts exhibited very high activity for the polymerization of ethylene, with activities as high as the range of 10(7) g of PE (mol of Ni)(-1) h(-1)

  DOI：

  10.1021/om200154a