[Dimethyl(propan-2-yloxy)silyl]formonitrile | 136934-68-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: [Dimethyl(propan-2-yloxy)silyl]formonitrile
• CAS: 136934-68-4
• 化学式: C₆H₁₃NOSi
• 分子量: 143.261
• InChiKey: HJAZPWNLASVZSU-UHFFFAOYSA-N

物化性质

• 沸点：
  -52 °C(Press: 18-2049 Torr)
• 密度：
  0.8417 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.68
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  33
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [Dimethyl(propan-2-yloxy)silyl]formonitrile 在 三氟化锑 作用下， 以65.6%的产率得到fluoro-dimethyl-propan-2-yloxysilane
  参考文献：
  名称：

  Organosilicon and organophosphorus compounds with pseudohalogen groups. 1. Synthesis of alkoxydimethylsilyl cyanides and their reactions with metal fluorides

  摘要：

  Alkoxydimethylsilyl cyanides were synthesized by the exchange reaction of the corresponding alkoxydimethylchlorosilanes with trimethylsilyl cyanide, and also by the reaction of the former compounds with HCN in the presence of triethylamine (the latter method is preferential). Reactions of silyl cyanides with SbF3 and ZnF2 were studied. It was found that the reaction of silyl cyanides with SBF3 leads to the formation of Me2SiF2 and the corresponding alkoxydimethylfluorosilanes, which were also obtained by counter-synthesis from alkoxydimethylsilylchlorosilanes and metal fluorides (SbF3, ZnF2, CsF). Dimethylfluorosilyl cyanide was obtained by the reaction of silyl cyanides with ZnF2.

  DOI：

  10.1007/bf00961242
• 作为产物：
  描述：

  氢氰酸 、 一缩二乙二醇一(2-乙基已基)醚 在 三乙胺 作用下， 以 乙醚 为溶剂， 以75.1%的产率得到[Dimethyl(propan-2-yloxy)silyl]formonitrile
  参考文献：
  名称：

  Organosilicon and organophosphorus compounds with pseudohalogen groups. 1. Synthesis of alkoxydimethylsilyl cyanides and their reactions with metal fluorides

  摘要：

  Alkoxydimethylsilyl cyanides were synthesized by the exchange reaction of the corresponding alkoxydimethylchlorosilanes with trimethylsilyl cyanide, and also by the reaction of the former compounds with HCN in the presence of triethylamine (the latter method is preferential). Reactions of silyl cyanides with SbF3 and ZnF2 were studied. It was found that the reaction of silyl cyanides with SBF3 leads to the formation of Me2SiF2 and the corresponding alkoxydimethylfluorosilanes, which were also obtained by counter-synthesis from alkoxydimethylsilylchlorosilanes and metal fluorides (SbF3, ZnF2, CsF). Dimethylfluorosilyl cyanide was obtained by the reaction of silyl cyanides with ZnF2.

  DOI：

  10.1007/bf00961242

文献信息

• Organosilicon and organophosphorus compounds with pseudohalide groups
  作者：A. A. Krolevets、V. V. Antipova、P. V. Petrovskii、I. V. Martynov

  DOI：10.1007/bf00863934

  日期：1992.1

  The reactions of alkoxydimethylsilyl cyanides with some tetracoordinated phosphorus chlorides and fluorides were investigated. It was shown that the investigated reactions are realized primarily with the replacement of two halogen atoms by functional groups. The transformations of the phosphorus acid cyanides obtained with metal fluorides were studied.
• KROLEVETS, A. A.;ANTIPOVA, V. V.;MARTYNOV, P. V., IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1593-1597
  作者：KROLEVETS, A. A.、ANTIPOVA, V. V.、MARTYNOV, P. V.

  DOI：——

  日期：——