2,2'-((1-(o-tolylamino)butane-1,3-diylidene)bis(azaneylylidene))dibenzoic acid | 1239857-87-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2'-((1-(o-tolylamino)butane-1,3-diylidene)bis(azaneylylidene))dibenzoic acid
• CAS: 1239857-87-4
• 化学式: C₂₅H₂₃N₃O₄
• 分子量: 429.475
• InChiKey: PQBYAWPCXXRHRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.72
• 重原子数：
  32.0
• 可旋转键数：
  7.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  111.35
• 氢给体数：
  3.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  2'-甲基乙酰乙酰苯胺 、 邻氨基苯甲酸 以 乙醇 为溶剂， 生成 2,2'-((1-(o-tolylamino)butane-1,3-diylidene)bis(azaneylylidene))dibenzoic acid
  参考文献：
  名称：

  Ruthenium(III) tetradentate Schiff-base complexes: spectral, catalytic, and its biocidal efficacy

  摘要：

  New six-coordinate ruthenium(III) Schiff-base complexes of general formula [Ru(X)(PPh3)(L)] (where X = Cl/Br and L = mononucleating bibasic tetradentate ligand derived by condensing actetoacetanilide/acetoacetotoludide with o-aminophenol/o-aminothiophenol/o-aminobenzoic acid in 1 : 2 molar ratio in ethanol) have been synthesized and characterized by physico-chemical and spectroscopic methods. The new ruthenium(III) complexes possess 2NO/2NS metal binding sites and are catalysts for the oxidation of alcohols using molecular oxygen as co-oxidant and in C-C coupling reactions. These complexes possess good biocidal (antibacterial and antifungal) activity.

  DOI：

  10.1080/00958972.2010.487937