Pd[(μ-O2CMe)2Ag(HO2CMe)2]2 | 1308661-15-5

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Pd[(μ-O2CMe)2Ag(HO2CMe)2]2
• 英文别名: Palladate-tetrakis[|I-(acetato-|EO:|EO')]bis[bis(acetato-|EO)silver]-, hydrogen (1:4)；disilver;hydron;palladium(2+);octaacetate
• CAS: 1308661-15-5
• 化学式: C₁₆H₂₈Ag₂O₁₆Pd
• 分子量: 798.545
• InChiKey: BSCWCAZSZPCIJL-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Pd[(μ-O2CMe)2Ag(HO2CMe)2]2 、 邻菲罗啉 以 苯 为溶剂， 以75%的产率得到(Phen)Pd(OAc)₂
  参考文献：
  名称：

  Novel heterometallic palladium–silver complex

  摘要：

  The reaction between Pd(3)(OOCMe)(6) and Ag(2)(OOCMe)(2) afforded the first palladium-silver heterometallic acetate-bridged complex Pd(II)[(mu-OOCMe)(2)Ag(I)(HOOCMe)(2)](2) (1). The molecular geometry and electronic structure of 1 were studied by single-crystal XRD and quantum-chemical DFT calculations. Thermal transformations of 1 in vacuo and under Ar, H(2) produced PdAg alloy nanoparticles characterized with powder XRD and EXAFS. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.003
• 作为产物：
  描述：

  palladium diacetate 、 Ag2(μ-O2CMe)2 以 溶剂黄146 为溶剂， 以50%的产率得到Pd[(μ-O2CMe)2Ag(HO2CMe)2]2
  参考文献：
  名称：

  Novel heterometallic palladium–silver complex

  摘要：

  The reaction between Pd(3)(OOCMe)(6) and Ag(2)(OOCMe)(2) afforded the first palladium-silver heterometallic acetate-bridged complex Pd(II)[(mu-OOCMe)(2)Ag(I)(HOOCMe)(2)](2) (1). The molecular geometry and electronic structure of 1 were studied by single-crystal XRD and quantum-chemical DFT calculations. Thermal transformations of 1 in vacuo and under Ar, H(2) produced PdAg alloy nanoparticles characterized with powder XRD and EXAFS. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.003