Metal nitrido- and oxo-complexes. Part I. Complexes of ruthenium and osmium
作者:William P. Griffith、David Pawson
DOI:10.1039/dt9730001315
日期:——
properties of the new complexes Cs2[Ru(N)X5] and R[M(N)X4](M = Ru or Os; R = Ph4As or Bun4N; X = Cl or Br) are described. New binuclear nitrido-bridged complexes of ruthenium(IV) with carbonyl, cyanide, and chelate ligands, the polymeric nitrido-bridged species [Os(N)Br4]nn– and [Os3(N)2X11–(NH3)3]3–(X = Cl or Br), and oxo- and dioxo-complexes of ruthenium are also reported. The structures of the species
新配合物Cs 2 [Ru(N)X 5 ]和R [M(N)X 4 ](M = Ru或Os; R = Ph 4 As或Bu n 4 N; X = Cl或Br)进行说明。钌(新双核次氮桥连络合物IV)与羰基,氰化物,和螯合配体,聚合次氮桥联物种[OS(N)溴4 ] ñ ñ -和[O的3(N)2 X 11 -(NH 3)3 ] 3–(X = Cl或Br),还报道了钌的氧代和二氧代配合物。根据振动光谱和其他特性讨论了物种的结构。