Be(3-phenylthioacetylacetonate)2 | 66041-16-5

• 英文名称: Be(3-phenylthioacetylacetonate)2
• CAS: 66041-16-5
• 化学式: C₂₂H₂₂BeO₄S₂
• 分子量: 423.558
• InChiKey: PODNSSWXEBNPHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  beryllium(II) chloride 、 3-(phenylthio)pentane-2,4-dione 在 sodium acetate 作用下， 以 乙醇 、 水 为溶剂， 以83%的产率得到Be(3-phenylthioacetylacetonate)2
  参考文献：
  名称：

  3-R-Thio- and 3-R-Oxy-substituted metal acetylacetonates

  摘要：

  New S- and O-substituted metal acetylacetonates were prepared from phenylthio-, butylthio-, benzenesulfonato-, and 3-acetoxyacetylacetone and appropriate metal salts. The spectral characteristics of the compounds were obtained. The effect of the alpha-substituent on the stability of the chelates under the conditions of chromatographic separation on silica gel was revealed. The reactivity of the acetate group bonded to the chelate ring is decreased, which does not allow preparation of new substituted complexes by common transformations of esters.

  DOI：

  10.1134/s1070363207110035