molybdenum-rhenium | 60719-51-9

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: molybdenum-rhenium
• 英文别名: rhenium molybdenum；molybdenum;rhenium
• CAS: 60719-51-9
• 化学式: MoRe
• 分子量: 282.147
• InChiKey: NZPGFUCQQUDSQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  Re1.18Mo2.82O6(OMe)12 在 H₂ 作用下， 以 neat (no solvent, solid phase) 为溶剂， 生成 molybdenum-rhenium
  参考文献：
  名称：

  Alkoxide Route to Re- and Mo-Based Metallic and Oxide Materials

  摘要：

  The oxomethoxo complexes Re4O2(OMe)(16), Re4O6(OMe)(12), and Re4-xMoxO6(OMe)(12) (x = 0.10, 2.82) are prepared via anodic dissolution of rhenium and molybdenum in methanol in the presence of LiCl. The phase composition of the solid products obtained by decomposing the synthesized complexes in oxidizing inert, and reducing atmospheres is examined by x-ray diffraction. The results demonstrate that, by decomposing these complexes in the range 150-500degreesC, one can obtain Re-based metallic and oxide materials: ReO3, monoclinic ReO2, orthorhombic (Re,Mo)O-2 solid solutions, metallic Re powder, and Re-Mo alloys, including nanocrystalline powders.

  DOI：

  10.1023/b:inma.0000016094.25482.92

文献信息

• Tochitskiy; Smolyaninova; Belyavskiy, Physics of Metals and Metallography, <hi>1989</hi>, vol. 67, # 6, p. 36 - 39
  作者：Tochitskiy、Smolyaninova、Belyavskiy、Sviridovich、Tyavlovskiy

  DOI：——

  日期：——
• Optical absorption of Mo-based alloys
  作者：Madoka Tokumoto、H. D. Drew

  DOI：10.1103/physrevb.30.4322

  日期：——
• Measurements of critical magnetic fields and resistance for a phase Mo-Re
  作者：H.R. Khan、Ch.J. Raub、K. Lüders、G. Roth

  DOI：10.1016/0022-5088(80)90293-3

  日期：1980.2
• Alkoxide Route to Re- and Mo-Based Metallic and Oxide Materials
  作者：P. A. Shcheglov、D. V. Drobot、Yu. V. Syrov、A. S. Mal'tseva

  DOI：10.1023/b:inma.0000016094.25482.92

  日期：2004.2

  The oxomethoxo complexes Re4O2(OMe)(16), Re4O6(OMe)(12), and Re4-xMoxO6(OMe)(12) (x = 0.10, 2.82) are prepared via anodic dissolution of rhenium and molybdenum in methanol in the presence of LiCl. The phase composition of the solid products obtained by decomposing the synthesized complexes in oxidizing inert, and reducing atmospheres is examined by x-ray diffraction. The results demonstrate that, by decomposing these complexes in the range 150-500degreesC, one can obtain Re-based metallic and oxide materials: ReO3, monoclinic ReO2, orthorhombic (Re,Mo)O-2 solid solutions, metallic Re powder, and Re-Mo alloys, including nanocrystalline powders.