propyl 1-(propylsulfinyl)propyl disulfide

• 分子结构分类: 有机化合物 - 有机硫化合物 - 亚砜
• 英文名称: propyl 1-(propylsulfinyl)propyl disulfide
• 英文别名: Propyl 1-(propylsulfinyl)propyl disulfide；1-(propyldisulfanyl)-1-propylsulfinylpropane
• 化学式: C₉H₂₀OS₃
• 分子量: 240.455
• InChiKey: NIBWKLISDHVING-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  86.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  S-丙基丙烷-1-硫代亚磺酸盐 以 水 、 苯 为溶剂， 反应 36.0h， 以9.6%的产率得到propyl 1-(propylsulfinyl)propyl disulfide
  参考文献：
  名称：

  Allium Chemistry:  Synthesis of 1-[Alk(en)ylsulfinyl]propyl Alk(en)yl Disulfides (Cepaenes), Antithrombotic Flavorants from Homogenates of Onion (Allium cepa)

  摘要：

  A series of 1-[alk(en)ylsulfinyl]propyl alk(en)yl disulfides (alpha-sulfinyl disulfides) of structure RS(O)CHEtSSR', R, R' = Me, (E,Z)-MeCH=CH, n-Pr, and CH2=CHCH2, termed cepaenes, have been synthesized by a variety of routes including oxidation of 1-[alk(en)ylthio]propyl alk(en)yl disulfides, RSCHEtSSR', termed deoxycepaenes. The cepaenes are identical to compounds isolated from homogenates of onion (Allium cepa) and to compounds identified in these homogenates by liquid chromatography/mass spectrometry, while the deoxycepaenes are identical to compounds found in Allium distilled oils and in other materials: The antithrombotic activities for several cepaenes are reported.

  DOI：

  10.1021/jf9705126

文献信息

• <i>Allium</i> Chemistry:  Synthesis of 1-[Alk(en)ylsulfinyl]propyl Alk(en)yl Disulfides (Cepaenes), Antithrombotic Flavorants from Homogenates of Onion (<i>Allium cepa</i>)
  作者：Eric Block、Harsh Gulati、David Putman、Deyou Sha、Niannian You、Shu-Hai Zhao

  DOI：10.1021/jf9705126

  日期：1997.11.1

  A series of 1-[alk(en)ylsulfinyl]propyl alk(en)yl disulfides (alpha-sulfinyl disulfides) of structure RS(O)CHEtSSR', R, R' = Me, (E,Z)-MeCH=CH, n-Pr, and CH2=CHCH2, termed cepaenes, have been synthesized by a variety of routes including oxidation of 1-[alk(en)ylthio]propyl alk(en)yl disulfides, RSCHEtSSR', termed deoxycepaenes. The cepaenes are identical to compounds isolated from homogenates of onion (Allium cepa) and to compounds identified in these homogenates by liquid chromatography/mass spectrometry, while the deoxycepaenes are identical to compounds found in Allium distilled oils and in other materials: The antithrombotic activities for several cepaenes are reported.