2-Tert-butyl-4-[(3-tert-butyl-4-hydroxyphenyl)-phenylmethyl]phenol | 57138-53-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 2-Tert-butyl-4-[(3-tert-butyl-4-hydroxyphenyl)-phenylmethyl]phenol
• CAS: 57138-53-1
• 化学式: C₂₇H₃₂O₂
• 分子量: 388.55
• InChiKey: WOFFQWIGWBMFPL-UHFFFAOYSA-N

物化性质

• 沸点：
  484.2±40.0 °C(Predicted)
• 密度：
  1.070±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  29
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  ortho-tert-butylphenoxymagnesium bromide 、 N-苄叉苯胺 以 苯 为溶剂， 反应 24.0h， 以93%的产率得到2-Tert-butyl-4-[(3-tert-butyl-4-hydroxyphenyl)-phenylmethyl]phenol
  参考文献：
  名称：

  醛亚胺与酚镁的协调反应中的邻位选择性

  摘要：

  来自芳族醛的N-芳基亚胺在苯中与邻叔丁基苯氧基溴化镁反应，通过两个连续的对位区域特异性过程生成4,4'-亚芳基双酚，而N-烷基亚胺在相同条件下主要生成邻位区域选择性反应，生成2,2 ′-亚芳基双酚。

  DOI：

  10.1016/s0040-4039(00)87712-6

文献信息

• CURABLE RESIN COMPOSITION, CURABLE RESIN MOLDED BODY, CURED RESIN MOLDED BODY, METHOD FOR PRODUCING EACH OF SAME, AND LAMINATE BODY
  申请人：LINTEC CORPORATION

  公开号：US20140350187A1

  公开（公告）日：2014-11-27

  Provided is a curable resin composition comprising a thermoplastic resin (A) that includes a cyclic structure in its main chain, and has a glass transition temperature (Tg) of 140° C. or more, and a monofunctional curable monomer (B). The present invention provides: a cured resin formed article that has heat resistance and low birefringence, a method for producing the same, a curable resin composition and a curable resin formed article that are useful as a raw material for producing the cured resin formed article, and a laminate that includes a layer formed of a cured resin.

  提供的是一种可治愈树脂组合物，包括热塑性树脂（A），其主链中包含环状结构，并具有140℃或更高的玻璃化转变温度（Tg），以及单官能团可固化单体（B）。本发明提供了具有耐热性和低双折射率的固化树脂成型品，其生产方法，作为生产固化树脂成型品的原材料有用的可固化树脂组合物和可固化树脂成型品，以及包括由固化树脂形成的层的层压板。
• GAS-BARRIER FILM, PROCESS FOR PRODUCING SAME, MEMBER FOR ELECTRONIC DEVICE, AND ELECTRONIC DEVICE
  申请人：LINTEC Corporation

  公开号：EP2620278A9

  公开（公告）日：2014-10-29

  The present invention provides a gas barrier film including a base layer, and a gas barrier layer that is provided on at least one side of the base layer, the base layer including a resin having a glass transition temperature (Tg) of more than 130°C, the gas barrier layer being formed of a material that includes at least an oxygen atom and a silicon atom, a surface layer part of the gas barrier layer having an oxygen atom content rate of 60 to 75%, a nitrogen atom content rate of 0 to 10%, and a silicon atom content rate of 25 to 35%, based on a total content rate of oxygen atoms, nitrogen atoms, and silicon atoms, and the surface layer part of the gas barrier layer having a film density of 2.4 to 4.0 g/cm3. Also provided are a process for producing the same, an electronic device member that includes the gas barrier film, and an electronic device that includes the electronic device member. The gas barrier film of the invention exhibits an excellent gas barrier capability, excellent transparency, excellent bending resistance, and excellent heat resistance.

  本发明提供了一种气体阻隔薄膜，包括基底层和至少设置在基底层一侧的气体阻隔层，基底层包括玻璃化转变温度（Tg）大于130℃的树脂，气体阻隔层由至少包括氧原子和硅原子的材料形成、气体阻隔层的表层部分，根据氧原子、氮原子和硅原子的总含量，氧原子含量率为 60%至 75%，氮原子含量率为 0%至 10%，硅原子含量率为 25%至 35%，气体阻隔层的表层部分的薄膜密度为 2.4至4.0克/立方厘米。此外，本发明还提供了用于生产本发明的工艺、包含该气体阻挡层薄膜的电子设备部件以及包含该电子设备部件的电子器件。本发明的气体阻隔薄膜具有出色的气体阻隔能力、出色的透明度、出色的抗弯曲性和出色的耐热性。
• GAS BARRIER FILM, METHOD FOR PRODUCING SAME, GAS BARRIER FILM LAMINATE, MEMBER FOR ELECTRONIC DEVICES, AND ELECTRONIC DEVICE
  申请人：Lintec Corporation

  公开号：EP2774755A1

  公开（公告）日：2014-09-10

  The present invention provides: a gas barrier film comprising a cured resin layer and a gas barrier layer, the gas barrier layer being provided on at least one side of the cured resin layer, the cured resin layer being a layer formed of a cured product of a curable resin composition that includes (A) a thermoplastic resin having a glass transition temperature (Tg) of 140°C or more, and (B) a curable monomer, the gas barrier film having a water vapor transmission rate of 1 g/m2/day or less at a temperature of 40°C and a relative humidity of 90%; a method for producing the gas barrier film; a gas barrier film laminate comprising the gas barrier film; an electronic device member comprising the gas barrier film; an electronic device member comprising the gas barrier film laminate; an electronic device comprising the electronic device member. Since the gas barrier film and the gas barrier film laminate of the present invention exhibits excellent heat resistance, excellent solvent resistance, excellent interlayer adhesion, and an excellent gas barrier capability, has a low birefringence, and exhibits excellent optical isotropy, the gas barrier film and the gas barrier film laminate may suitably be used as an electronic device member.

  本发明提供：一种气体阻隔薄膜，包括固化树脂层和气体阻隔层，气体阻隔层至少设置在固化树脂层的一侧、 固化树脂层是由可固化树脂组合物的固化产物形成的层，该树脂组合物包括（A）玻璃化转变温度（Tg）为 140℃或以上的热塑性树脂和（B）可固化单体、 该气体阻隔薄膜在温度为 40°C 和相对湿度为 90% 时的水蒸气透过率为 1 克/平方米/天或更低； 生产该气体阻隔薄膜的方法； 包含该气体阻隔薄膜的气体阻隔薄膜层压板； 包含该气体阻隔薄膜的电子装置部件； 包含该气体阻隔薄膜层压板的电子装置部件； 包含该电子装置部件的电子装置。 由于本发明的气体阻隔薄膜和气体阻隔薄膜层压板具有优异的耐热性、优异的耐溶剂性、优异的层间粘合性和优异的气体阻隔能力，具有低双折射性和优异的光学各向同性，因此本发明的气体阻隔薄膜和气体阻隔薄膜层压板可适当地用作电子设备部件。
• GAS BARRIER LAMINATE
  申请人：LINTEC CORPORATION

  公开号：EP3904079A1

  公开（公告）日：2021-11-03

  Provided is a gas barrier laminate which, even when produced by a coating method, has a reduced thickness, excellent optical isotropy, and excellent gas barrier property, and can be suitably used as a member for an electronic device, the gas barrier laminate including, a process film, a base layer, and a gas barrier layer, in this order, the base layer being a layer formed of a cured product of a curable resin composition containing a polymer component (A), and a curable monomer (B), the polymer component (A) having the glass transition temperature of 250°C or higher.

  本发明提供了一种气体阻隔层压板，该气体阻隔层压板即使通过涂覆方法生产，也能减小厚度、具有优异的光学各向同性和优异的气体阻隔性能，并可适当用作电子设备的部件，该气体阻隔层压板包括：工艺膜、基底层和气体阻隔层，依次为基底层是由含有聚合物成分（A）的可固化树脂组合物的固化产物和可固化单体（B）形成的层，聚合物成分（A）的玻璃化转变温度为 250°C 或更高。
• CASNATI, G.;POCHINI, A.;PUGLIA, G.;UNGARO, R., TETRAHEDRON LETT., 1982, 23, N 37, 3803-3806
  作者：CASNATI, G.、POCHINI, A.、PUGLIA, G.、UNGARO, R.

  DOI：——

  日期：——