羟基甲基氧代锡烷 | 753-61-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 羟基甲基氧代锡烷
• 英文名称: methylstannoic acid
• 英文别名: Methyl-stannonsaeure；Methylstannonic Acid；Methylstannonsaeure；Hydroxymethyloxostannane；hydroxy-methyl-oxotin
• CAS: 753-61-7
• 化学式: CH₄O₂Sn
• 分子量: 166.752
• InChiKey: FVQPYHHKHUVHDR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.47
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  羟基甲基氧代锡烷 在 HBr 作用下， 以 neat (no solvent) 为溶剂， 生成 methyltin(IV) tribromide
  参考文献：
  名称：

  Inter‐ and intramolecular interactions and rotational tunneling of methyl groups in tetramethyltin

  摘要：

  Rotational tunneling of methyl groups in partially deuterated tetramethyltin compounds, (CH3)xSn(CD3)4−x with x=1 and 3, and in various isotopic mixtures, [(CH3)4Sn]x[Sn(CD3)4]1−x, x=0.027, 0.20, and 0.50, and [CH3Sn(CD3)3]x[Sn(CD3)4]1−x, x=0.10, respectively, has been studied using the inelastic neutron-scattering (INS) technique. Compared with the INS spectrum of fully protonated tetramethyltin, (CH3)4Sn, the spectra obtained in the present study show remarkable shifts and broadenings or splittings of tunnel lines. The interpretation of the INS results is based on the assumption that all partially deuterated compounds and isotopically mixed systems have the same crystal structure as pure (CH3)4Sn. Combining the INS results with a detailed discussion of the crystal structure, all features can be explained in terms of both the intra- and intermolecular interactions of methyl groups. The overall decrease of tunnel splittings with deuteration is explained by the reduction of the lattice parameter and the increased octopole moment of the CD3 groups. The interaction between different molecules is mediated by a subset of methyl group pairs only.

  DOI：

  10.1063/1.459950
• 作为产物：
  描述：

  tin(II) chloride dihdyrate 、 碘甲烷 在 KOH 、 CO₂ 作用下， 以 乙醇 、 水 为溶剂， 生成 羟基甲基氧代锡烷
  参考文献：
  名称：

  Inter‐ and intramolecular interactions and rotational tunneling of methyl groups in tetramethyltin

  摘要：

  Rotational tunneling of methyl groups in partially deuterated tetramethyltin compounds, (CH3)xSn(CD3)4−x with x=1 and 3, and in various isotopic mixtures, [(CH3)4Sn]x[Sn(CD3)4]1−x, x=0.027, 0.20, and 0.50, and [CH3Sn(CD3)3]x[Sn(CD3)4]1−x, x=0.10, respectively, has been studied using the inelastic neutron-scattering (INS) technique. Compared with the INS spectrum of fully protonated tetramethyltin, (CH3)4Sn, the spectra obtained in the present study show remarkable shifts and broadenings or splittings of tunnel lines. The interpretation of the INS results is based on the assumption that all partially deuterated compounds and isotopically mixed systems have the same crystal structure as pure (CH3)4Sn. Combining the INS results with a detailed discussion of the crystal structure, all features can be explained in terms of both the intra- and intermolecular interactions of methyl groups. The overall decrease of tunnel splittings with deuteration is explained by the reduction of the lattice parameter and the increased octopole moment of the CD3 groups. The interaction between different molecules is mediated by a subset of methyl group pairs only.

  DOI：

  10.1063/1.459950

文献信息

• Oxo carboxylate tin ladder clusters. A new structural class of organotin compounds
  作者：Robert R. Holmes、Charles G. Schmid、V. Chandrasekhar、Roberta O. Day、Joan M. Holmes

  DOI：10.1021/ja00239a022

  日期：1987.3

  the dimeric n-butyloxotin carboxylate compositions, [(n-BuSn(O)O2CR)2-n-BuSn(O2CR)3]2, 2 (R = Ph) and 3 (R = Me). These represent new substances and, as found by X-ray analysis, form a new structural class of organotin compounds for 2-4 having “unfolded drum” or “ladder” structures. The hexamer composition 1 exists in “drum” form. 119Sn NMR data show that the drum and ladder structures interconvert reversibly

  摘要 制备了六聚正丁氧锡苯甲酸酯 [n-BuSn(O)O2CC6H4NO2.2]6.3C6H6, 1 和二聚甲基氧锡环己酸酯 [(MeSn(O)O2CC6H11)2MeSn(O2CC6H11)3]2, 4,通过将锡酸与相应的羧酸缩合。正丁基锡的反应。三氯化物与相应羧酸的银盐得到二聚正丁基氧代锡羧酸盐组合物，[(n-BuSn(O)O2CR)2-n-BuSn(O2CR)3]2, 2 (R = Ph) 和 3 ( R = 我）。这些代表新物质，并且如通过 X 射线分析发现的那样，形成具有“展开的鼓”或“梯形”结构的 2-4 的新结构类别的有机锡化合物。六聚体组合物1以“鼓”形式存在。119Sn NMR数据表明鼓和梯形结构可逆地相互转换。1 在菱形/空间群 R3 中结晶，H = 15.283 (4) A, cH, = 34.683 (9) A，
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.1, 1, page 17 - 35
  作者：

  DOI：——

  日期：——
• GB871730
  申请人：——

  公开号：——

  公开（公告）日：——
• Holmes, Robert R.; Day, Roberta O.; Chandrasekhar, V., Phosphorus and Sulfur and the Related Elements, 1986, vol. 28, p. 91 - 98
  作者：Holmes, Robert R.、Day, Roberta O.、Chandrasekhar, V.、Shafeizad, Soheila、Harland, John J.、et al.

  DOI：——

  日期：——
• Day, Roberta O.; Chandrasekhar; Swamy, K. C. Kumara, Inorganic Chemistry, 1988, vol. 27, # 16, p. 2887 - 2893
  作者：Day, Roberta O.、Chandrasekhar、Swamy, K. C. Kumara、Holmes, Joan M.、Burton, Sarah D.、Holmes, Robert R.

  DOI：——

  日期：——