trans-bis(dimethyl sulfide)tetrachloroplatinum(IV) | 55903-49-6

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: trans-bis(dimethyl sulfide)tetrachloroplatinum(IV)
• 英文别名: trans-Pt((CH3)2S)2Cl4；trans-tetrachlorobis(dimethyl sulfide) platinum(IV)；trans-[Pt(Me2S)2Cl2]；trans-(PtCl4(SMe2)2)；trans-[Pt(Me2S)2Cl4]；methylsulfanylmethane;tetrachloroplatinum
• CAS: 55903-49-6
• 化学式: C₄H₁₂Cl₄PtS₂
• 分子量: 461.163
• InChiKey: IKCDGDKGWSKOSK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  4.71
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  trans-bis(dimethyl sulfide)tetrachloroplatinum(IV) 在 吡啶 作用下， 以 乙腈 为溶剂， 以80%的产率得到trans-(PtCl₄(py)(SMe₂))
  参考文献：
  名称：

  Kukushkin, V. Yu.; Pan'kova, E. Yu.; Aleksandrova, E. A., Russian Journal of Inorganic Chemistry, 1990, vol. 35, p. 1013 - 1015

  摘要：

  DOI：
• 作为产物：
  描述：

  tetrakis(dimethyl-l4-sulfaneyl)platinum(VIII) dichloride hexachloroplatinate(IV) 以 solid 为溶剂， 生成 trans-bis(dimethyl sulfide)tetrachloroplatinum(IV)
  参考文献：
  名称：

  Kukushkin, Yu. N.; Krupenko, I. N.; Postnikova, E. S., Journal of applied chemistry of the USSR, 1981, vol. 54, p. 1027 - 1030

  摘要：

  DOI：

文献信息

• Hydrosilylation of Siloxanes in the Presence of Pt(II) and Pt(IV) Complexes
  作者：D. A. de Vekki、V. N. Spevak、E. A. Kuchaev、N. K. Skvortsov

  DOI：10.1007/s11176-005-0505-6

  日期：2005.11

  The catalytic activities of Pt(II) and Pt(IV) complexes with various ligands and counterions in hydrosilylation of 1,3-divinyl-1,1,3,3-tetramethyldisiloxane with 1,1,3,3-tetramethyldisiloxanes are compared.

  在1,3-二乙烯基-1,1,3,3-四甲基二硅氧烷与1,1,3,3-四甲基二硅氧烷的水解加成反应中，比较了具有不同配体和反离子的Pt(II)和Pt(IV)配合物的催化活性。
• Reduction of (imine)Pt(IV) to (imine)Pt(II) Complexes with Carbonyl-Stabilized Phosphorus Ylides
  作者：Gabriele Wagner、Tatyana B. Pakhomova、Nadezhda A. Bokach、João J. R. Fraústo da Silva、Jose Vicente、Armando J. L. Pombeiro、Vadim Yu. Kukushkin

  DOI：10.1021/ic000769c

  日期：2001.3.1

  other Pt(II)/Pt(IV) couples, and the ylides Ph3P=CHCO2R are introduced as mild and selective reducing agents of wide applicability for the conversion of Pt(IV) to Pt(II) species in nonaqueous media, a route that is especially useful in the case of compounds that cannot be prepared directly from Pt(II) precursors, and for the generation of systematic series of Pt(II)/Pt(IV) complexes for biological studies

  报道了一种难以获得的（亚胺）Pt（II）化合物的新方法，该方法涉及通过羰基稳定的磷化磷（Ph3P = CHCO2R）在非水中还原相应的基于Pt（IV）的亚胺。媒体。中性（亚氨基）Pt（IV）化合物[PtCl4 [NH = C（Me）ON = CR1R2] 2]之间的反应[R1R2 = Me2，（CH2）4，（ ）5，（Me）C（Me）= NOH]，[PtCl4 [NH = C（Me）ONR2] 2]（R = Me，Et， Ph），（R1 = H; R2 = Ph或C6H4Me; R3 = Me）以及阴离子型铂（IV ）配合物（Ph3PCH2Ph）[PtCl5 [NH = C（Me）ON = CR2]] [R2 = Me2，（ ）4，（ ）5]和1当量的Ph3P = CHCO2R（R = Me，Et）在在温和的条件下（约4小时，室温）选择性地得到铂（II）产物（具有优良的分离
• Reaction of platinum complexes with (+)-α-pinene and (+)-limonene. Synthesis, molecular structure, and catalytic activity of dichloro(η4-[p-mentha-1,8{9}-diene])platinum(II)
  作者：D. A. de Vekki、V. M. Uvarov、V. K. Bel’skii、N. K. Skvortsov

  DOI：10.1134/s1070363206080226

  日期：2006.8

  The transformations of platinum(II) and platinum(IV) complexes with inner- and outer-sphere ligands by the action of (+)-alpha-pinene and (+)-limonene were studied. Reduction of the metal complex is the main process whose rate increases in the following outer-sphere ligand series: (Me2SO)(2)H+ < Et3NH+ < K+ < H+. The reaction of K2PtCl4 with alpha-pinene gave cis-terpine monohydrate and dichloro-eta(4)-[p-mentha-1,8(9)-diene]platinum(II), and their structure was proved by X-ray analysis. The complex belongs to monoclinic crystal system, the Pt-Cl and Pt-C bonds therein have different lengths, the ClPtCl angle is 85.88 degrees, and the C=C bond plane is orthogonal to the square coordination core. Dichloro-eta(4)-[p-mentha-1,8(9)-diene]platinum(II) was tested as catalyst in the hydrosilylation of acetophenone with diphenylsilane.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Pt: MVol.D, 135, page 302 - 304
  作者：

  DOI：——

  日期：——
• Kukushkin, Vadim Yu.; Belsky, Vitalii K.; Konovalov, Vadim E., Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 69, # 12, p. 103 - 118
  作者：Kukushkin, Vadim Yu.、Belsky, Vitalii K.、Konovalov, Vadim E.、Aleksandrova, Elena A.、Pankova, Elena Yu.、Moiseev, Anatolii I.

  DOI：——

  日期：——