{(η5-C5(CH3)5)Ru(CO)2Br} | 90420-05-6

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: {(η5-C5(CH3)5)Ru(CO)2Br}
• 英文别名: (η(5)-C5Me5)(CO)2RuBr；[Ru(CO)2Br(η5-pentamethylcyclopentadienyl)]
• CAS: 90420-05-6
• 化学式: C₁₂H₁₅BrO₂Ru
• 分子量: 372.224
• InChiKey: ZTWJXRPHIIBBTM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  phosphorus 、 {(η5-C5(CH3)5)Ru(CO)2Br} 以 xylene 为溶剂， 以3.3%的产率得到(η5-pentamethylcyclopentadienyl)(η5-cyclo-pentaphosphorus)ruthenium
  参考文献：
  名称：

  Scherer, Otto J.; Brueck, Thomas; Wolmershaeuser, Gotthelf, Chemische Berichte, 1988, vol. 121, p. 935 - 938

  摘要：

  DOI：
• 作为产物：
  描述：

  [η(5)-Me5C5Ru(CO)2]2 在 bromine 作用下， 以 二氯甲烷 为溶剂， 以80%的产率得到{(η5-C5(CH3)5)Ru(CO)2Br}
  参考文献：
  名称：

  Weber, Lothar; Reizig, Klaus; Boese, Roland, Organometallics, 1985, vol. 4, # 12, p. 2097 - 2101

  摘要：

  DOI：

文献信息

• Transition-Metal-Substituted Acyl Phosphanes and Phosphaalkenes. 33.¹ Transition-Metal-Substituted Arsaalkenes. 3.² Reactivity of Metallodisilylphosphanes and -arsanes (η⁵-C₅Me₅)(CO)₂M−E(SiMe₃)₂ (M = Fe, Ru; E = P, As) toward Carbon Disulfide. Formation of Metallophosphaalkenes, Metalloarsaalkenes, and 1,3,4-Thiadiphospholes
  作者：Lothar Weber、Stefan Uthmann、Bärbel Torwiehe、Ralf Kirchhoff、Roland Boese and Dieter Bläser

  DOI：10.1021/om970124t

  日期：1997.7.1

  the metallodisilylarsanes (η5-C5Me5)(CO)2M−As(SiMe3)2 (M = Fe, Ru) (11a,b) were converted to stable metalloarsaalkenes 12a,b by exposure to CS2. Pentacarbonylchromium complexes 13a,b were accessible by reaction with [(Z)-cyclooctene]Cr(CO)5. The X-ray structure analysis of 13a revealed the molecule as the first η1-arsaalkene complex.

  （η的反应5 -C 5我5）（CO）2 FEP（森达3）2（图4a）与二硫化碳，得到不稳定metallophosphaalkene（η 5 -C 5我5）（CO）2 FEP C [SSiMe 3 ] 2（5a），其通过挤出双（三甲基甲硅烷基）硫化物而分解为双金属化的1,3,4-噻二磷8a。瞬态metallophosphaalkene 5A被截获作为可分离[（CO）5 Cr]的-adduct 6A通过用治疗[（Z）-环辛烯] Cr（CO）5。类似地，metallodisilylarsanes（η 5 -C 5我5）（CO）2 M-作为（森达3）2（M =铁，钌）（11A，B）转换为稳定metalloarsaalkenes 12A，12B通过暴露于CS 2。五羰基铬配合物13a，b可通过与[（Z）-环辛烯] Cr（CO）5反应获得。的X射线结构分析图13A揭示了分子作为第一η 1 -arsaalkene复杂。
• Unbridged homo and hetero dinuclear complexes of Group 6 and 8 metals: synthesis, characterization and comparison of X-ray crystallographic data
  作者：Thomas Straub*、Matti Haukka、Tapani A. Pakkanen*

  DOI：10.1016/s0022-328x(00)00428-9

  日期：2000.10

  Several novel compounds of the type Cp/Cp*(CO)3MM′(CO)nCp/Cp* (M=Cr, Mo, W; M′=Ru, n=2; M′=Mo, n=3; Cp=C5H5, Cp*=C5Me5) were synthesized, characterized, their structures compared and preliminary reactivity studies were carried out. The main investigations were focused on the molybdenum and ruthenium containing heterobimetallic compounds Cp(CO)3MoRu(CO)2Cp (1) as well as Cp(CO)3MoRu(CO)2Cp* (2) and

  类型的CP / CP *（CO）的几个新化合物3 MM'（CO）ñ的CP / CP *（M =铬，钼，W; M'= RU，Ñ = 2; M'=沫，Ñ＝ 3；合成CP ＝ C 5 H 5，CP * ＝ C 5 Me 5），表征，比较它们的结构并进行初步反应性研究。主要研究都集中在钼和含钌化合物的异CP（CO）3 MoRu（CO）2的CP（1）以及CP（CO）3 MoRu（CO）2的CP *（2）和的CP *（CO）3 MoRu（CO）2 CP（3），后两种代表“混合金属混合配体”类型的配合物，而前两种（1）在两个金属核上具有相同的配体。首次详细阐述了具有钼和钌金属核的未桥接双金属配合物的性能比较。新颖的CP（CO）3 MoMo（CO）3的CP *（4）由两个相同的金属芯和的'混合'的配体。在建立后者的合成路线之后，通过用CP * Mo（CO）3 Br（5）处理NaMo（CO）3 CP制备图4。1与卤化物或AlCl
• Facile conversion of (η5-C5R5) M(CO)2-halide complexes to halomethyl, alkoxymethyl, and cyanomethyl derivatives (R  H, CH3; M  Fe, Ru; halide  Cl, Br, I)
  作者：John L. Hubbard、William K. McVicar

  DOI：10.1016/0022-328x(92)83185-k

  日期：1992.5

  The CpM(CO)2-X complexes (M = Fe, Ru; X = Cl, Br; CP = eta-5-C5H5, Cp* = eta-5-C5Me5) are completely converted to the corresponding halomethyl derivatives over a 20-30 min period when ethereal diazomethane is added dropwise in the presence of Cu powder. Product work-up involves only simple extraction of the crude product with hexane followed by recrystallization at - 40-degrees-C. Formation of iodomethyl derivatives from iodide precursors requires considerably longer CH2N2 addition times and cannot be completely freed of the starting iodide complexes. Fortunately, iodomethyl complexes can be prepared in 80-95% isolated yield by treating the chloromethyl or bromomethyl derivatives with NaI in acetone/Et2O. The CpFe(CO)2CH2I and Cp*Fe(CO)2CH2I complexes are the most sensitive, decomposing rapidly to polymethylene and the parent iodide complexes upon standing at room temperature. Metathetical reactions of the halomethyl complexes to give alkoxymethyl and cyanomethyl derivatives are described.
• Jutzi, Peter; Mix, Andreas, Chemische Berichte, 1990, vol. 123, p. 1043 - 1046
  作者：Jutzi, Peter、Mix, Andreas

  DOI：——

  日期：——
• Nagashima, Hideo; Mukai, Katsunori; Itoh, Kenji, Organometallics, 1984, vol. 3, # 8, p. 1314 - 1315
  作者：Nagashima, Hideo、Mukai, Katsunori、Itoh, Kenji

  DOI：——

  日期：——