2,4,6-tripropoxy-1,3,5-triazine | 29263-10-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2,4,6-tripropoxy-1,3,5-triazine
• 英文别名: 2,4,6-Tris-propyloxy-s-triazin；2,4,6-Tri-n-propyloxy-1,3,5-triazin；Tripropoxy-[1,3,5]triazin；tri(n-propyl) cyanurate
• CAS: 29263-10-3
• 化学式: C₁₂H₂₁N₃O₃
• 分子量: 255.317
• InChiKey: OTFGKNPRQHOROP-UHFFFAOYSA-N

物化性质

• 熔点：
  30-33 °C
• 沸点：
  125-127 °C(Press: 0.9 Torr)
• 密度：
  1.063±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  18
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  66.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,4,6-tripropoxy-1,3,5-triazine 在 三氟化硼 、 溶剂黄146 、 xylene 作用下， 生成 1,3-dipropyl-[1,3,5]triazinane-2,4,6-trione
  参考文献：
  名称：

  US2830051

  摘要：

  公开号：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 tin(ll) chloride 作用下， 生成 2,4,6-tripropoxy-1,3,5-triazine
  参考文献：
  名称：

  US2682541

  摘要：

  公开号：

文献信息

• Photosensitive Resin Composition, Cured Product Thereof and Production Method of Printed Circuit Board Using the Same
  申请人：Ishigaki Satoru

  公开号：US20070218305A1

  公开（公告）日：2007-09-20

  There are provided a novel photosensitive resin composition, a cured film of which has ample flexibility, and which yields an insulating protective coating having superior soldering heat resistance, thermal degradation resistance and electroless gold plating resistance. The photosensitive resin composition as claimed in the present invention comprises: a photopolymerizeable component containing a urethane acrylate compound (A) and a compound (B) having an ethylenic unsaturated group other than said urethane acrylate compound (A), a thermosetting resin (C), a photopolymerization initiator (D) and a thermal polymerization catalyst (E); wherein, said urethane acrylate compound (A) is the reaction product of an isocyanate compound (a-1) of the following general formula (1): CH 2 ═CH—COO—R—NCO  (1) (wherein, R represents a hydrocarbon group having 1 to 30 carbon atoms) with a polyhydroxy compound (a-2).

  本发明提供了一种新型的光敏树脂组合物，其固化膜具有充足的柔韧性，并且产生的绝缘保护涂层具有优异的焊接耐热性，热降解耐性和无电镀金耐性。本发明所述的光敏树脂组合物包括：含有尿素丙烯酸酯化合物（A）和除所述尿素丙烯酸酯化合物（A）以外的具有乙烯基不饱和基团的化合物（B）的光聚合组分，热固性树脂（C），光聚合引发剂（D）和热聚合催化剂（E）；其中，所述尿素丙烯酸酯化合物（A）是以下一般式（1）的异氰酸酯化合物（a-1）和多羟基化合物（a-2）的反应产物：CH2═CH—COO—R—NCO  （1）（其中，R代表具有1至30个碳原子的碳氢基团）。
• PROCESS FOR PRODUCING LAUROLACTAM
  申请人：Ishihara Kazuaki

  公开号：US20100324283A1

  公开（公告）日：2010-12-23

  Disclosed is a method for producing laurolactam from cyclododecanone and hydroxylamine in a simple process and with high efficiency. The method comprises the following steps (a) to (e): (a) reacting cyclododecanone with hydroxylamine in an aqueous solution in the presence of an excess amount of cyclododecanone or a solvent to produce cyclododecanone oxime; (b) separating the reaction mixture obtained after the oxime-forming step into an oil and an aqueous phases and collecting a solution of cyclododecanone oxime of the oil phase as; (c) removing dissolved water from the solution of cyclododecanone oxime which is collected as an oily phase in the oil/aqueous phase separation step; (d) producing laurolactam from cyclododecanone oxime by rearrangement reaction using an aromatic-ring containing compound as a rearrangement catalyst; and (e) separating the produced laurolactam from the reaction mixture after the rearrangement step and purifying the laurolactam.

  本发明公开了一种从环十二酮和羟胺中简单高效地生产月桂内酰胺的方法。该方法包括以下步骤(a)至(e)：(a)在过量的环十二酮或溶剂存在下，将环十二酮与羟胺在水溶液中反应，生成环十二酮肟；(b)将生成肟化物的反应混合物分离成油相和水相，收集油相中的环十二酮肟溶液；(c)从收集的油相中去除溶解的水；(d)使用含芳香环的化合物作为重排催化剂，通过重排反应从环十二酮肟制备月桂内酰胺；(e)从重排步骤后的反应混合物中分离出制备的月桂内酰胺并对其进行纯化。
• Ag ₂₂ Nanoclusters with Thermally Activated Delayed Fluorescence Protected by Ag/Cyanurate/Phosphine Metallamacrocyclic Monolayers through In‐Situ Ligand Transesterification
  作者：Zhi‐Rui Yuan、Zhi Wang、Bao‐Liang Han、Cheng‐Kai Zhang、Shan‐Shan Zhang、Zhen‐Yu Zhu、Jiu‐Hong Yu、Tian‐Duo Li、Ying‐Zhou Li、Chen‐Ho Tung、Di Sun

  DOI：10.1002/anie.202211628

  日期：2022.11.7

  Ag22 nanoclusters protected by a metallamacrocyclic monolayer were synthesized in high yields by in-situ ligand formation strategy. The high-electron-affinity triazine-based cyanurate ligands endow the clusters with unique core-shell interfacial bonding structure and donor-acceptor type electronic structure, resulting in the first mixed valence Ag0/I nanocluster with thermally activated delayed fluorescence

  通过原位配体形成策略，以高产率合成了四个由金属大环单层保护的同构 Ag 22纳米团簇。高电子亲和性三嗪基氰脲酸酯配体赋予团簇独特的核-壳界面键合结构和供体-受体型电子结构，形成第一个具有热激活延迟荧光（TADF）特性的混合价Ag 0/I纳米团簇.
• High efficiency polymerization catalyst component for use in the polymerization of propylene and higher alpha-olefins
  申请人：EXXON RESEARCH AND ENGINEERING COMPANY

  公开号：EP0149558A2

  公开（公告）日：1985-07-24

  An aliphatic hydrocarbon soluble mixed aluminum hydrocarbyl-Lewis base co-catalyst composition comprising (i) at least two different classes of aluminum hydrocarbyls the first being an aluminum hydrocarbyl halide, the second being an aluminum hydrocarbyl hydride and/or aluminum trialkyl and (ii) at least one Lewis base represented by the formula: wherein each Y can be -OR', -NR2 and R' with the proviso that at least two be -OR' or -NR2, Z is an alkylene radical forming a 5 or 6 membered ring with the carbonyldioxy group or Z is alkyl substituted alkylene group wherein the alkyl radical can have from 1 to 8 carbon atoms, R is an aryl, allyl or alkyl group having from 1 to 20 carbon atoms and R' is an alkyl, cycloalkyl, aryl or aralkyl radical having from 1 to 20 carbon atoms. The co-catalyst is employed with a titanium halide catalyst for the polymerization of olefins to obtain a advantageous balance of catalytic activity and polymer product stereoregularity.

  一种脂族烃溶性混合烃基铝-路易斯碱助催化剂组合物，包括(i)至少两类不同的烃基铝，第一类是烃基卤化铝，第二类是烃基氢化铝和/或三烷基铝，以及(ii)至少一种由式表示的路易斯碱： 其中每个 Y 可以是-OR'、-NR2 和 R'，但至少有两个是-OR'或-NR2，Z 是与羰基二氧基形成 5 或 6 成员环的亚烷基，或者 Z 是烷基取代的亚烷基，其中烷基可以具有 1 至 8 个碳原子，R 是具有 1 至 20 个碳原子的芳基、烯丙基或烷基，R'是具有 1 至 20 个碳原子的烷基、环烷基、芳基或芳烷基。 该助催化剂与卤化钛催化剂一起用于烯烃的聚合，可在催化活性和聚合物产品的立体规整性之间取得有利的平衡。
• FLAME-RETARDANT POLYAMIDE COMPOSITE MATERIAL WITH HIGH RIGIDITY
  申请人：Showa Denko Kabushiki Kaisha

  公开号：EP1024172A1

  公开（公告）日：2000-08-02

  The present invention relates to a highly-rigid, flame-resistant polyamide composite material that is applicable to various uses such as in materials for electric and electronic parts, automobile parts, materials for house appliances, mechanical parts, and the like. The polyamide composite material according to the present invention is characterized in comprising (a) polyamide resin; (b) silicate complex comprising a layered silicate and triazine compound; (c) fibrous reinforcement; and (d) flame retarder. The polyamide composite material according to the present invention exhibits a high flame resistance, a superior performance with respect to its mechanical property, thermal property, dimensional stability, and reduced warp.

  本发明涉及一种高刚性阻燃聚酰胺复合材料，适用于各种用途，如电气和电子 部件材料、汽车部件、家用电器材料、机械部件等。根据本发明的聚酰胺复合材料，其特征在于包括：(a) 聚酰胺树脂；(b) 由层状硅酸盐和三嗪化合物组成的硅酸盐复合物；(c) 纤维增强材料；(d) 阻燃剂。根据本发明的聚酰胺复合材料具有高阻燃性，在机械性能、热性能、尺寸稳定性和减少翘曲方面性能优越。