diiron | 12596-01-9

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: diiron
• 英文别名: iron dimer；iron
• CAS: 12596-01-9
• 化学式: Fe₂
• 分子量: 111.694
• InChiKey: NJFMNPFATSYWHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  diiron 、 15N-氨 以 solid matrix 为溶剂， 生成
  参考文献：
  名称：

  Kauffman; Hauge; Margrave, High temperature science, 1984, vol. 17, p. 237 - 249

  摘要：

  DOI：
• 作为产物：
  描述：

  铁粉 以 solid matrix 为溶剂， 生成 diiron
  参考文献：
  名称：

  Ozin, Geoffrey A.; McCaffrey, John G., Inorganic Chemistry, 1983, vol. 22, # 9, p. 1397 - 1399

  摘要：

  DOI：

文献信息

• Formation of metal cluster ions by gas-phase ion-molecule reactions: The bond energies of Cr2+ AND Mn2+
  作者：R. Houriet、T. Vulpius

  DOI：10.1016/0009-2614(89)87130-1

  日期：1989.2

  Ion-molecule reactions occurring in Cr(CO)6, Fe(CO)5, and Mn2(CO)10 systems are carried out in a Fourier transform ion cyclotron resonance (FTICR) spectrometer. Abundant intensities of bare metal cluster ions can be formed by employing a multiple pulse sequence including selective ejections and photodissociation. In subsequent collisional activation experiments, the binding energies of Cr2+ and Mn2+

  Cr（CO）6，Fe（CO）5和Mn 2（CO）10系统中发生的离子分子反应是在傅立叶变换离子回旋共振（FTICR）光谱仪中进行的。可以通过采用包括选择性喷射和光解离的多脉冲序列来形成大量的裸金属簇离子。在随后的碰撞活化实验中，Cr 2 +和Mn 2 +的结合能分别确定为1.6±0.2 eV和2.1±0.3 eV，后者与先前报道的值相矛盾。
• Photochemistry of iron atoms and dimers with ethylene in cryogenic matrixes. The FT-IR spectrum of ethenyliron hydride
  作者：Zakya H. Kafafi、Robert H. Hauge、John L. Margrave

  DOI：10.1021/ja00311a054

  日期：1985.12
• Ligand Effect on the Growth and the Digestion of Co Nanocrystals
  作者：Anna C. S. Samia、Kylee Hyzer、John A. Schlueter、Chang-Jin Qin、J. Samuel Jiang、Samuel D. Bader、Xiao-Min Lin

  DOI：10.1021/ja044419r

  日期：2005.3.1

  The reaction product of cobalt carbonyl decomposition depends on the concentration of the oleic acid ligand. With a low concentration of ligand, nanocrystals nucleate and grow to large ferromagnetic particles through the process of Ostwald ripening and coalescence coarsening. With a high concentration of ligand, stable cluster complexes are formed. Addition or removal of ligand from the reaction products can interchange the formation of cluster complexes and nanocrystals.
• Collision‐induced dissociation processes of Nb⁺₄ and Fe⁺₄: Fission vs evaporation
  作者：S. K. Loh、Li Lian、David A. Hales、P. B. Armentrout

  DOI：10.1063/1.455455

  日期：1988.7

  Collision-induced dissociation (CID) of Nb+4 and Fe+4 with Xe has been studied over an energy range of 0–20 eV with a new instrument designed to study cold cluster ions. The energy dependences of the cross sections are presented. It is found that the lowest energy pathway for Nb+4 CID is fragmentation into molecular ions, or fission. Analysis of this process yields D0(Nb+2–Nb2)=4.3±0.3 eV. Fe+4, on the other hand, fragments only by sequential loss of Fe. Analysis of the lowest energy process gives D0(Fe+3–Fe)=1.8±0.2 eV. No evidence for molecular Fen fragments is observed.
• Loh, S. K.; Lian, Li; Hales, David A., Journal of Chemical Physics, 1988, vol. 89, p. 3378 - 3379
  作者：Loh, S. K.、Lian, Li、Hales, David A.、Armentrout, P. B.

  DOI：——

  日期：——