N-1-trifluoromethyl-1-trimethylsiloxy-2,2,2-trifluoroethyl-N'-trimethylsilylcarbodiimide | 79317-72-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: N-1-trifluoromethyl-1-trimethylsiloxy-2,2,2-trifluoroethyl-N'-trimethylsilylcarbodiimide
• 英文别名: N-(2-trimethylsilyloxyperfluoropropan-2-yl)-N'-trimethylsilylcarbodiimide
• CAS: 79317-72-9
• 化学式: C₁₀H₁₈F₆N₂OSi₂
• 分子量: 352.427
• InChiKey: YYGZRACXDLEGLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.67
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  34
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  二(三甲基硅基)碳酰二亚胺 、 六氟丙酮 反应 1.0h， 以80%的产率得到N-1-trifluoromethyl-1-trimethylsiloxy-2,2,2-trifluoroethyl-N'-trimethylsilylcarbodiimide
  参考文献：
  名称：

  Synthesis of functionalized fluorine-containing trimethylsilylcarbodiimides

  摘要：

  New functionalized polyfluorinated carbodiimides RFN=C=NSiMe3 were prepared by the reactions of bis(trimethylsilyl)carbodiimide with electrophilic reagents. The structures of the resulting compounds were confirmed by H-1, C-13, Si-29, N-14, N-15, and O-17 NMR spectroscopy.

  DOI：

  10.1007/bf02496267

文献信息

• Fetyukhin, V. N.; Voek, M. V.; Dergunov, Yu. I., Journal of general chemistry of the USSR, 1981, vol. 51, # 7, p. 1431
  作者：Fetyukhin, V. N.、Voek, M. V.、Dergunov, Yu. I.、Samarai, L. I.

  DOI：——

  日期：——
• FETYUXIN V. N.; BOBK M. V.; DERGUNOV YU. I.; SAMARAJ L. I., ZH. OBSHCH. XIMII, 1981, 51, HO 7, 1678-1679
  作者：FETYUXIN V. N.、 BOBK M. V.、 DERGUNOV YU. I.、 SAMARAJ L. I.

  DOI：——

  日期：——
• Synthesis of functionalized fluorine-containing trimethylsilylcarbodiimides
  作者：D. V. Romanov、T. V. Strelkova、Yu. A. Strelenko、N. V. Vasil'ev

  DOI：10.1007/bf02496267

  日期：1999.4

  New functionalized polyfluorinated carbodiimides RFN=C=NSiMe3 were prepared by the reactions of bis(trimethylsilyl)carbodiimide with electrophilic reagents. The structures of the resulting compounds were confirmed by H-1, C-13, Si-29, N-14, N-15, and O-17 NMR spectroscopy.