(β-hydroxyethyl)diallylisocyanurate | 839-88-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: (β-hydroxyethyl)diallylisocyanurate
• 英文别名: 3,5-diallyl-1-(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione；1,3-Diallyl-5-(2-hydroxyethyl)-isocyanurat；1,3-diallyl-5-(2-hydroxy-ethyl)-[1,3,5]triazinane-2,4,6-trione；1,3-Diallyl-5-(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione；1-(2-hydroxyethyl)-3,5-bis(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione
• CAS: 839-88-3
• 化学式: C₁₁H₁₅N₃O₄
• 分子量: 253.258
• InChiKey: ZNRKKTBDWFDNSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  81.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  二正丁基氧化锡 、 (β-hydroxyethyl)diallylisocyanurate 以 neat (no solvent) 为溶剂， 以95%的产率得到(dibutylstannylene)bis(oxyethylene) bis[diallyl isocyanurate]
  参考文献：
  名称：

  Gordetsov, A. S.; Pereshein, V. V.; Skobeleva, S. E., Journal of general chemistry of the USSR, 1982, vol. 52, p. 2435 - 2439

  摘要：

  DOI：
• 作为产物：
  描述：

  monosodium 1,3-diallylisocyanurate 、 2-氯乙醇 生成 (β-hydroxyethyl)diallylisocyanurate
  参考文献：
  名称：

  TEISSIER, R.;CLAMENS, S.

  摘要：

  DOI：

文献信息

• Synthesis of N-[2-(3,5-Diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)­ethyl]ureas and -Carbamates
  作者：O. A. Kolyamshin、Yu. N. Mitrasov、V. A. Danilov、M. V. Kuz’min、K. Yu. Ivanova

  DOI：10.1134/s1070428023040073

  日期：2023.4

  4,6-trione with phenyl isocyanate afforded 2-(3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)ethyl phenylcarbamate, and the alkylation of 3,5-diallyl-1,3,5-triazinane-2,4,6-trione sodium salt with bis(2-chloroethyl) hexane-1,6-diyldi­carbamate produced bis[2-(3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)ethyl] hexane-1,6-diyldicarbamate. Physical and spectroscopic properties of the synthesized isocyanurates

  摘要 1-(2-氨基乙基)-3,5-二烯丙基-1,3,5-三嗪烷-2,4,6-三酮与异氰酸苯酯和六亚甲基二异氰酸酯反应，得到以前未知的含有一种或两种脲的异氰脲酸酯和双异氰脲酸酯片段，分别。3,5-二烯丙基-1-(2-羟乙基)-1,3,5-三嗪烷-2,4,6-三酮与异氰酸苯酯反应得到2-(3,5-二烯丙基-2,4,6 -三氧代-1,3,5-三嗪烷-1-基)乙基苯基氨基甲酸酯，以及3,5-二烯丙基-1,3,5-三嗪烷-2,4,6-三酮钠盐与双(2-氯乙基）己烷-1,6-二氨基甲酸酯生成双[2-(3,5-二烯丙基-2,4,6-三氧代-1,3,5-三嗪-1-基)乙基]己烷-1,6-二氨基甲酸酯。研究了合成的异氰脲酸酯和双异氰脲酸酯的物理和光谱性质。
• Improvement in or relating to aromatic polyamide film
  申请人：TEIJIN LIMITED

  公开号：EP0091778A2

  公开（公告）日：1983-10-19

  A process for producing an aromatic polyamide film, which comprises drawing an undrawn aromatic polyamide film biaxially at a draw ratio of at least 1.5 in a solvent mixture consisting of (a) 5% to 75% by weight of a good solvent of the aromatic polyamide and (b) 25% to 95% by weight of a non-solvent of the aromatic polyamide, and heat treating the drawn film, which contains at least 1% by weight, based on the weight of the film, of a good solvent of said aromatic polyamide, at a temperature of not lower than 150°C. An m-phenyleneisophthalamide polymer film having extremely excellent dimensional stability under moist conditions, which film has a density d of from 1.35 to 1.41 g/cm3 and principal refractive indices nα, nβ and nγ (nα > nβ, > nγ) for D-line of a wavelength of 589 nm satisfying the following formula:

  一种芳香族聚酰胺薄膜的生产工艺，包括将未拉伸的芳香族聚酰胺薄膜以至少 1.5 的拉伸比在混合溶剂中进行双向拉伸，混合溶剂包括(a)5%至 75%（按重量计）芳香族聚酰胺的良好溶剂和(b)25%至 95%（按重量计）芳香族聚酰胺的非溶剂，然后在不低于 150°C 的温度下对拉伸薄膜进行热处理，热处理后的薄膜含有至少 1%（按重量计）的芳香族聚酰胺良好溶剂。 一种在潮湿条件下具有极佳尺寸稳定性的间苯异酞酰胺聚合物薄膜，该薄膜的密度 d 为 1.35 至 1.41 克/立方厘米，对于波长为 589 纳米的 D 线的主折射率 nα、nβ 和 nγ（nα > nβ， > nγ）满足下式：
• Contact lens material
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0289797A2

  公开（公告）日：1988-11-09

  Disclosed herein is a contact lens material comprising a polymer obtained by reacting and polymerizing 15 - 100 wt.% of the following component (A) and 0 - 85 wt.% of the following component (B) and containing fluorinated side chains and urethane bonds: Component (A): A mixture of (1) a radical-polymerizable monomer containing at least one active hydrogen atom which can undergo an addition reaction with an isocyanate group, (2) a bifunctional or higher polyisocyanate compound and (3) a compound represented by Rf·(OH)n, Rf·COOH, Rf·NH₂ or Rf·CONH₂ wherein n stands for 1 or 2 and Rf means a fluorinated C₁₋₂₅-alkyl group, alkylphenyl group or phenyl group; or an addition reaction product thereof. Component (B): A monomer copolymerizable with the radical-­polymerizable monomer (1) of the component (A). The contact lens material has well-balanced properties among oxygen permeability, hardness, machinability, wearing comfortableness, etc.

  本发明公开了一种隐形眼镜材料，该材料包含一种聚合物，该聚合物是由 15-100 重量份的以下组分（A）和 0-85 重量份的以下组分（B）反应聚合而成，并含有氟化侧链和聚氨酯键： 组分（A）： (1) 含至少一个活性氢原子的可自由基聚合单体的混合物，该单体可与异氰酸酯基团发生加成反应、(2) 双官能度或更高的多异氰酸酯化合物和 (3) 由 Rf-(OH)n、Rf-COOH、Rf-NH₂ 或 Rf-CONH₂ 代表的化合物，其中 n 代表 1 或 2，Rf 指氟化 C₁₋₂₅-烷基、烷基苯基或苯基；或其加成反应产物。 组分 (B)： 可与组分（A）中可自由基聚合的单体（1）共聚的单体。 该隐形眼镜材料在透氧性、硬度、可加工性、佩戴舒适性等方面具有良好的平衡特性。
• Silicone Structure-Bearing Polymer, Resin Composition, and Photo-Curable Dry Film
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2631259A1

  公开（公告）日：2013-08-28

  A silicone structure-bearing polymer having a crosslinking group within the molecule, containing an isocyanurate structure bonded within the molecule, and having a Mw of 3,000-500,000 is provided. The polymer overcomes the stripping problem that a coating is stripped from metal wirings of Cu or Al, electrodes, and SiN substrates.

  本发明提供了一种有机硅结构聚合物，其分子内含有交联基团，分子内键合有异氰脲酸酯结构，且 Mw 在 3,000-500,000 之间。该聚合物克服了铜或铝金属线、电极和氮化硅基板涂层被剥离的问题。
• Resist underlayer composition, and method of forming patterns using the composition
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US10732504B2

  公开（公告）日：2020-08-04

  A resist underlayer composition and a method of forming patterns using the resist underlayer composition, the resist underlayer composition including a polymer including a moiety represented by Chemical Formula 1 and a moiety represented by Chemical Formula 2, and a solvent,

  一种抗蚀剂底层组合物和一种使用该抗蚀剂底层组合物形成图案的方法，该抗蚀剂底层组合物包括一种聚合物，其中包括化学式 1 所代表的分子和化学式 2 所代表的分子，以及一种溶剂、