(Butyltellanyl)(trimethyl)silane | 175660-78-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (Butyltellanyl)(trimethyl)silane
• 英文别名: butyltellanyl(trimethyl)silane
• CAS: 175660-78-3
• 化学式: C₇H₁₈SiTe
• 分子量: 257.905
• InChiKey: BZXZIVLTGBGWIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.74
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  [Pt(PEt₃)₃] 、 (Butyltellanyl)(trimethyl)silane 以 正己烷 为溶剂， 生成
  参考文献：
  名称：

  Extremely Facile Oxidative Addition of Silyl, Germyl, and Stannyl Tellurides and Other Chalcogenides to Platinum(0) Complexes. X-ray Structure of trans-Pt(4-PhC₆H₄Te)(SiMe₃)(PEt₃)₂

  摘要：

  DOI：

  10.1021/ja9713744

文献信息

• Butyltellurolate ligands in cluster synthesis: molecular structure of Ag6Te6, Ag32Te25 and Ag48Te36 complexes
  作者：John F. Corrigan、Dieter Fenske

  DOI：10.1039/cc9960000943

  日期：——

  BunTeSiMe3 reacts with silver(I) chloride in the presence of PEt3 to yield the following series of cluster complexes depending on the relative amount of phosphine used: [Ag6(µ3-TeBun)4(µ-TeBun)2(PEt3)4] 1, [Ag32(µ3-TeBun)18-Te7(PEt3)6] 2 and [Ag48(µ3-TeBun)24Te12(PEt3)14] 3; the molecular structures of 2 and 3 are described.

  BunTeSiMe3 在 PEt3 存在下与氯化银 (I) 反应，根据所用膦的相对量生成以下一系列簇络合物： [Ag6(µ3-TeBun)4(µ-TeBun)2(PEt3)4] 1 ，[Ag32(μ3-TeBun)18-Te7(PEt3)6] 2 和[Ag48(μ3-TeBun)24Te12(PEt3)14] 3;描述了2和3的分子结构。
• Semmelmann, Marcus; Fenske, Dieter; Corrigan, John F., Journal of the Chemical Society, Dalton Transactions, 1998, # 15, p. 2541 - 2545
  作者：Semmelmann, Marcus、Fenske, Dieter、Corrigan, John F.

  DOI：——

  日期：——
• Synthesis and structural characterisation of new copper–tellurium clusters: TeBuⁿ(SiMe₃) as a source of RTe^–and Te^2–ligands
  作者：John F. Corrigan、Silke Balter、Dieter Fenske

  DOI：10.1039/dt9960000729

  日期：——

  Reactions of cobalt(II) and copper(I) salts with the functionalised reagents alkyl- and aryl(trimethylsilyl)tellurium have been explored. The silylated reagents are found to be an excellent source of RTe(-) and Te2- ligands alike in high-nuclearity transition metal-tellurium clusters and the products isolated from the reaction mixtures have been structurally characterised by single-crystal X-ray analyses: [Co-6(mu(3)-Te)(8)(PPh(2)Pr(n))(6)] 1, [Cu-11(mu(3)-TeBu(n))(7)(mu(4)-TeBu(n))(2)(mu(7)-Te)(PPh(3))(5)] 2, [Cu-18(mu(3)-TeBu(n))(6)Te-6(PPr3n)(8)] 3, [Cu58Te32(PPh(3))(16)] 4 and [Cu23Te13(PEt(3))(12)] 5 have been synthesised. The formation of the complexes is highly dependent on the ancillary phosphine used. Cluster 1 consists of a non-bonded octahedral array of Co atoms with eight tellurium ligands capping the open Co-3 faces. Complexes 2-4 possess layered structures composed of Te atoms with Cu occupying peripheral and interlayer sites. The Te atoms in 5 form a body-centred icosahedron, with an overall near-spherical cluster framework.
• Extremely Facile Oxidative Addition of Silyl, Germyl, and Stannyl Tellurides and Other Chalcogenides to Platinum(0) Complexes. X-ray Structure of <i>trans</i>-Pt(4-PhC₆H₄Te)(SiMe₃)(PEt₃)₂
  作者：Li-Biao Han、Shigeru Shimada、Masato Tanaka

  DOI：10.1021/ja9713744

  日期：1997.8.1