Cd(ethyl xanthate)₂ | 21757-58-4

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Cd(ethyl xanthate)₂
• 英文别名: Cd(EX)₂；Cd-xanthate；bis(O-ethyldithiocarbonato)cadmium；Cadmium ethyl xanthate；cadmium(2+);ethoxymethanedithioate
• CAS: 21757-58-4
• 化学式: C₆H₁₀CdO₂S₄
• 分子量: 354.818
• InChiKey: LFMJCPXFFQURMB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.71
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  84.6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Cd(ethyl xanthate)₂ 反应 0.03h， 生成 cadmium sulphide
  参考文献：
  名称：

  Precursor dependent morphological and photo-catalytic behaviour of CdS nanostructures

  摘要：

  Cadmium complexes based on Xanthate and dithiocarbamate such as [Cd(ethyl xanthate)2], [Cd(morpholine-4-dithiocarbamate)(2)] and [Cd(piperazine1-dithiocarbamate)(2)] have been used as efficient single source precursors. The formation of CdS nanostructures have been achieved by solvothermal route of synthesis. Crystallographic and morphological characterization of synthesized nanomaterials has been done by X-ray diffraction (XRD) and electron microscopy [Transmission Electron Microscope (TEM)], respectively. Diffraction and electron microscope studies reveal the formation of wurtzite structured CdS nanostructures of various morphologies (nanorods and nanospheres). UV-vis absorption and Fourier transform infrared (FUR) spectroscopic studies have been carried for the detailed optical as well as qualitative analyses. It has been reported that the morphology of synthesized nanomaterials strongly depends upon the type of the precursor complexes. Photo-catalytic activity of the synthesized nano structures has been tested in visible irradiation using methylene blue (MB) dye as a test contaminant in aqueous media. Morphology dependent photo-catalytic activity of the synthesized nanomaterials has been studied in detail to explore the potential of prepared nanostructures to purify polluted water. (C) 2016 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2016.10.043
• 作为产物：
  描述：

  无水碳酸镉 、 potassium ethyl xanthogenate 以 水 为溶剂， 反应 0.75h， 生成 Cd(ethyl xanthate)₂
  参考文献：
  名称：

  Precursor dependent morphological and photo-catalytic behaviour of CdS nanostructures

  摘要：

  Cadmium complexes based on Xanthate and dithiocarbamate such as [Cd(ethyl xanthate)2], [Cd(morpholine-4-dithiocarbamate)(2)] and [Cd(piperazine1-dithiocarbamate)(2)] have been used as efficient single source precursors. The formation of CdS nanostructures have been achieved by solvothermal route of synthesis. Crystallographic and morphological characterization of synthesized nanomaterials has been done by X-ray diffraction (XRD) and electron microscopy [Transmission Electron Microscope (TEM)], respectively. Diffraction and electron microscope studies reveal the formation of wurtzite structured CdS nanostructures of various morphologies (nanorods and nanospheres). UV-vis absorption and Fourier transform infrared (FUR) spectroscopic studies have been carried for the detailed optical as well as qualitative analyses. It has been reported that the morphology of synthesized nanomaterials strongly depends upon the type of the precursor complexes. Photo-catalytic activity of the synthesized nano structures has been tested in visible irradiation using methylene blue (MB) dye as a test contaminant in aqueous media. Morphology dependent photo-catalytic activity of the synthesized nanomaterials has been studied in detail to explore the potential of prepared nanostructures to purify polluted water. (C) 2016 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2016.10.043

文献信息

• The synthesis of new bimetallic complex salts by halide/sulfur chelate cross transfer: X-ray crystal structures of the salts [Ni(S2CNEt2)(dppe)]2[HgBr4], [Pt(S2CNEt2)(dppe)]2[CdCl4], [Co(S2CNEt2)2(dppe)]2[Cl3ZnO:(Ph)2PCH2CH2P(Ph)2:OZnCl3] and [Pd(S2CNnBu2)(bipy)]2[CdCl4]
  作者：George Exarchos、Stephen D Robinson、Jonathan W Steed

  DOI：10.1016/s0277-5387(01)00885-3

  日期：2001.11

  [Zn(S2CNEt2)2] in the presence of (S2CNEt2)2 affords the novel complex [Co(S2CNEt2)2(dppe)]2[Cl3ZnO:(Ph)2PCH2CH2P(Ph)2:OZnCl3]. A selection of these salts have been fully characterised by elemental analysis and spectroscopic techniques, the remainder have been identified by spectroscopic methods alone. X-ray crystal structures are reported for the salts [Ni(S2CNEt2)(dppe)]2 [HgBr4], [Pt(S2CNEt2)(dppe)]2[CdCl4]

  摘要镍和铂配合物[MX2（dppe）]（X = Cl，Br）与二价和三价金属二乙基二硫代氨基甲酸酯[M'（S2CNEt2）n]（M'= Pb，Zn，Cd，Hg，Ni ，MoO 2，VO，n ＝ 2； M′＝ Co，Fe，Mn，n ＝ 3）得到盐[M（S 2 CNEt 2）（dppe）] 2 [M′X 4]；涉及[Cu（S2CNEt2）2]和[Ag（S2CNEt2）]的反应生成的盐形式为[M（S2CNEt2）（dppe）] [M'X2]（M'= Cu，Ag）。顺式[RuCl2（dppm）2]，[CoCl2（dppe）]和[PdX2（bipy）]络合物同样与相同的二硫代氨基甲酸酯反应形成盐[Ru（S2CNEt2）（dppe）2] 2 [M'Cl4] [ Co（S2CNEt2）2（dppe）] 2 [M'Cl4]和[Pd（S2CNnBu2）（bipy）] 2 [M'X4]。涉及其他S-螯合物的配
• 硫化镉前驱体的合成及其在太阳能电池中的应 用
  申请人：中国科学院宁波材料技术与工程研究所

  公开号：CN103265566B

  公开（公告）日：2016-05-11

  本发明公开了硫化镉前驱体的合成及其在太阳能电池中的应用，具体地，本发明公开了一种含镉，不同碳链的黄原酸作为第一配体和1,10–菲啰啉（或其衍生物）作为第二配体的小分子半导体材料，其制备方法，及其在太阳能电池中的应用。该材料具有式1所示的结构，其中，各基团的定义如说明书中所述。用所述的式1化合物制备的半导体材料性能优越，非常适合用于太阳能电池部件的制造和生产。
• Synthesis of CdSe/ZnS Core/Shell Semiconductor Nanowires
  申请人：US Nano LLC

  公开号：US20150028288A1

  公开（公告）日：2015-01-29

  The present disclosure provides systems, processes, articles of manufacture, and compositions that relate to core/shell semiconductor nanowires. Specifically, the disclosure provides a novel semiconductor material, CdSe/ZnS core/shell nanowires, as well as a method of preparation thereof. The disclosure also provides a new continuous flow method of preparing core/shell nanowires, including CdSe/CdS core/shell nanowire and CdSe/ZnS core/shell nanowires.

  本公开提供了与核/壳半导体纳米线相关的系统、过程、制造物品和组成物。具体而言，本公开提供了一种新型半导体材料，即CdSe/ZnS核/壳纳米线，以及其制备方法。本公开还提供了一种新的连续流制备核/壳纳米线的方法，包括CdSe/CdS核/壳纳米线和CdSe/ZnS核/壳纳米线。
• Ansari, Mohammad A.; Mahler, Charles H.; Chorghade, Gayatri S., Inorganic Chemistry, 1990, vol. 29, # 19, p. 3832 - 3839
  作者：Ansari, Mohammad A.、Mahler, Charles H.、Chorghade, Gayatri S.、Lu, Ying-Jie、Ibers, James A.

  DOI：——

  日期：——
• Precursor dependent morphological and photo-catalytic behaviour of CdS nanostructures
  作者：Balwinder Kaur、Karamjit Singh、Ashok Kumar Malik

  DOI：10.1016/j.dyepig.2016.10.043

  日期：2017.2

  Cadmium complexes based on Xanthate and dithiocarbamate such as [Cd(ethyl xanthate)2], [Cd(morpholine-4-dithiocarbamate)(2)] and [Cd(piperazine1-dithiocarbamate)(2)] have been used as efficient single source precursors. The formation of CdS nanostructures have been achieved by solvothermal route of synthesis. Crystallographic and morphological characterization of synthesized nanomaterials has been done by X-ray diffraction (XRD) and electron microscopy [Transmission Electron Microscope (TEM)], respectively. Diffraction and electron microscope studies reveal the formation of wurtzite structured CdS nanostructures of various morphologies (nanorods and nanospheres). UV-vis absorption and Fourier transform infrared (FUR) spectroscopic studies have been carried for the detailed optical as well as qualitative analyses. It has been reported that the morphology of synthesized nanomaterials strongly depends upon the type of the precursor complexes. Photo-catalytic activity of the synthesized nano structures has been tested in visible irradiation using methylene blue (MB) dye as a test contaminant in aqueous media. Morphology dependent photo-catalytic activity of the synthesized nanomaterials has been studied in detail to explore the potential of prepared nanostructures to purify polluted water. (C) 2016 Elsevier Ltd. All rights reserved.