Trichlorogallane;trimethylarsane | 59400-54-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Trichlorogallane;trimethylarsane
• 英文别名: trichlorogallane;trimethylarsane
• CAS: 59400-54-3
• 化学式: C₃H₉AsCl₃Ga
• 分子量: 296.108
• InChiKey: RPCILPOKPNVVLW-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  3.06
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三甲基胂 、 氯化镓 以 乙醚 为溶剂， 以76%的产率得到Trichlorogallane;trimethylarsane
  参考文献：
  名称：

  Preparation, Characterization, and Structural Systematics of Diphosphane and Diarsane Complexes of Gallium(III) Halides

  摘要：

  The diphosphane O-C6H4(PMe2)(2) reacts with GaX3 (X = Cl, Br, or l) in a 1:1 molar ratio in dry toluene to give trans-[GaX2{o-C6H4(PMe2)(2)}(2)][GaX4], the cations of which contain the first examples of six-coordinate gallium in a phosphane complex. The use of a 1:2 ligand/GaCl3 ratio produced [GaCl2{o-C6H4(PMe2)(2)}][GaCl4], containing a pseudotetrahedral cation, and similar pseudotetrahedral [GaX2{o-C6H4(PPh2)(2)}](GaX4] complexes are the only products isolated with the bulkier O-C6H4(PPh2)(2). On the other hand, Et2P(CH2)(2)PEt2, which has a flexible aliphatic backbone, formed [(X3Ga)(2){mu-Et2P(CH2)(2)PEt2}], in which the ligand bridges two pseuclotetrahedral gallium centers. The diarsane, O-C6H4(AsMe2)(2), formed [GaX2{o-C6H4(AsMe2)(2)}][GaX4], also containing pseudotetrahedral cations, and in marked contrast to the diphosphane analogue, no six-coordinate complexes form; a very rare example where these two much studied ligands behave differently towards a common metal acceptor. The complexes [(l(3)Ga)Au-Ph2As(CH2)(2)AsPh2}] and [GaX3(AsMe3)] are also described. The X-ray structures of trans-[GaX2{o-C6H4(PME2)(2)}(2)][GaX4] (X = Cl, Br or 1), [GaCl2{o-C6H4(PPh2)(2)}][GaCl4], [GaX(2)10-C6H4(AsMe2)2J][GaX41 (X = Cl or 1), [(l(3)Ga)(2){U-Ph2As(CH2)(2)AsPh2}], and [GaX3(AsMe3)] (X = Cl, Br or 1) are reported, and the structural trends are discussed. The solution behavior of the complexes has been explored using a combination of P-31{H-1} and Ga-71 NMR spectroscopy.

  DOI：

  10.1021/ic700895r

文献信息

• Preparation, Characterization, and Structural Systematics of Diphosphane and Diarsane Complexes of Gallium(III) Halides
  作者：Fei Cheng、Andrew L. Hector、William Levason、Gillian Reid、Michael Webster、Wenjian Zhang

  DOI：10.1021/ic700895r

  日期：2007.8.1

  The diphosphane O-C6H4(PMe2)(2) reacts with GaX3 (X = Cl, Br, or l) in a 1:1 molar ratio in dry toluene to give trans-[GaX2o-C6H4(PMe2)(2)}(2)][GaX4], the cations of which contain the first examples of six-coordinate gallium in a phosphane complex. The use of a 1:2 ligand/GaCl3 ratio produced [GaCl2o-C6H4(PMe2)(2)}][GaCl4], containing a pseudotetrahedral cation, and similar pseudotetrahedral [GaX2o-C6H4(PPh2)(2)}](GaX4] complexes are the only products isolated with the bulkier O-C6H4(PPh2)(2). On the other hand, Et2P(CH2)(2)PEt2, which has a flexible aliphatic backbone, formed [(X3Ga)(2)mu-Et2P(CH2)(2)PEt2}], in which the ligand bridges two pseuclotetrahedral gallium centers. The diarsane, O-C6H4(AsMe2)(2), formed [GaX2o-C6H4(AsMe2)(2)}][GaX4], also containing pseudotetrahedral cations, and in marked contrast to the diphosphane analogue, no six-coordinate complexes form; a very rare example where these two much studied ligands behave differently towards a common metal acceptor. The complexes [(l(3)Ga)Au-Ph2As(CH2)(2)AsPh2}] and [GaX3(AsMe3)] are also described. The X-ray structures of trans-[GaX2o-C6H4(PME2)(2)}(2)][GaX4] (X = Cl, Br or 1), [GaCl2o-C6H4(PPh2)(2)}][GaCl4], [GaX(2)10-C6H4(AsMe2)2J][GaX41 (X = Cl or 1), [(l(3)Ga)(2)U-Ph2As(CH2)(2)AsPh2}], and [GaX3(AsMe3)] (X = Cl, Br or 1) are reported, and the structural trends are discussed. The solution behavior of the complexes has been explored using a combination of P-31H-1} and Ga-71 NMR spectroscopy.