bismuth(III) oxoformate | 60762-84-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bismuth(III) oxoformate
• 英文别名: bismuth oxide formate；bismuth formate；formic acid ; bismuth-formate oxide；Ameisensaeure; Wismut-formiat-oxid；(Formyloxy)bismuthanone；oxobismuthanyl formate
• CAS: 60762-84-7
• 化学式: BiO*CHO₂
• 分子量: 269.998
• InChiKey: SCORKTFNANALLP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.88
• 重原子数：
  5
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  bismuth(III) oxoformate 以 neat (no solvent) 为溶剂， 生成 bismuth(III) oxide
  参考文献：
  名称：

  The precipitation of basic bismuth formate from homogeneous solution and the determination of bismuth in presence of lead

  摘要：

  DOI：

  10.1039/an9608500216
• 作为产物：
  描述：

  bismuth(III) oxide 在 formic acid 作用下， 以 甲酸 为溶剂， 生成 bismuth(III) oxoformate
  参考文献：
  名称：

  Aurivillius, B., Acta Chemica Scandinavica (1947), 1955, vol. 9, p. 1213 - 1218

  摘要：

  DOI：

文献信息

• Enhanced Visible Light Photocatalytic Activity of Br-Doped Bismuth Oxide Formate Nanosheets
  作者：Xin Feng、Wen Cui、Junbo Zhong、Xiaoying Liu、Fan Dong、Yuxin Zhang

  DOI：10.3390/molecules201019189

  日期：——

  A facile method was developed to enhance the visible light photocatalytic activity of bismuth oxide formate (BiOCOOH) nanosheets via Br-doping. The as-prepared samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, the Brunauer–Emmett–Teller surface area, UV-vis diffuse reflectance spectroscopy, photoluminescence spectra, and N2 adsorption-desorption isotherms measurement. The Br− ions replaced the COOH− ions in the layers of BiOCOOH, result in a decreased layer distance. The photocatalytic activity of the as-prepared materials was evaluated by removal of NO in qir at ppb level. The results showed that the Br-doped BiOCOOH nanosheets showed enhanced visible light photocatalytic activtiy with a NO removal of 37.8%. The enhanced activity can be ascribed to the increased visible light absorption and the promoted charge separation.

  通过Br掺杂，开发了一种简便的方法来提高有机酸铋氧化物（BiOCOOH）纳米片在可见光下的光催化活性。所制备的样品通过X射线衍射、扫描电子显微镜、透射电子显微镜、X射线光电子能谱、Brunauer-Emmett-Teller比表面积、紫外-可见漫反射光谱、光致发光光谱和氮气吸附-脱附等温线进行了表征。Br⁻离子替换了BiOCOOH层中的COOH⁻离子，导致层间距减小。通过在空气中的ppb级NO去除率评价了所制备材料的光催化活性。结果显示，Br掺杂的BiOCOOH纳米片在可见光下的光催化活性得到增强，NO去除率达到37.8%。活性的增强可归因于可见光吸收增加和电荷分离促进。
• An efficient visible-light photocatalyst made from a nonpolar layered semiconductor by grafting electron-withdrawing organic molecules to its surface
  作者：Benyan Xu、Yang An、Yuanyuan Liu、Baibiao Huang、Xiaoyan Qin、Xiaoyang Zhang、Ying Dai、Myung-Hwan Whangbo

  DOI：10.1039/c6cc07849d

  日期：——

  A nonpolar inorganic layered semiconductor becomes an efficient visible-light photocatalyst when its surface layer becomes polar by chemically attaching electron-withdrawing 4-substituted thiophenolates -S-C6H4Z (Z= NO2, COOH, Cl, Br, H, CH3,...

  当其表面层由化学附着吸电子的4-取代的苯硫酚变为极性非极性无机层状半导体成为一种有效的可见光光催化剂- SC 6 H ^ 4 Z（Z = NO 2，COOH，氯，溴，H，CH 3，...
• Origin of organic gaseous products formed in the thermal decomposition of formates
  作者：A. Górski、A. Kraśnicka

  DOI：10.1007/bf01905178

  日期：1987.7
• Panchot, S.; Duval, C., Analytica Chimica Acta, 1951, vol. 5, p. 170 - 184
  作者：Panchot, S.、Duval, C.

  DOI：——

  日期：——
• Kallmann, S., 1941, vol. 13, p. 897 - 900
  作者：Kallmann, S.

  DOI：——

  日期：——