bis(chloromethyl)tetramethyldisiloxane | 18645-21-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: bis(chloromethyl)tetramethyldisiloxane
• 英文别名: 1,1-Bis-chlormethyl-tetramethyl-disiloxan；Bis(chloromethyl)-tetramethyldisiloxane；bis(chloromethyl)-methyl-trimethylsilyloxysilane
• CAS: 18645-21-1
• 化学式: C₆H₁₆Cl₂OSi₂
• 分子量: 231.269
• InChiKey: UTFVHGDIJZRFJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.97
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bis(chloromethyl)tetramethyldisiloxane 、 苯胺 生成 1,1-Bis-phenylaminomethyl-tetramethyl-disiloxan
  参考文献：
  名称：

  Synthesis and spectroscopic study of chloromethyl derivatives of silanes and siloxanes

  摘要：

  DOI：

  10.1007/bf00908492
• 作为产物：
  描述：

  双(氯甲基)甲基氯硅烷 、 sodium trimethylsilanolate 以 苯 为溶剂， 生成 bis(chloromethyl)tetramethyldisiloxane
  参考文献：
  名称：

  Synthesis and spectroscopic study of chloromethyl derivatives of silanes and siloxanes

  摘要：

  DOI：

  10.1007/bf00908492

文献信息

• Oligomeric aliphatic-aromatic ether containing phthalonitrile resins
  作者：Matthew Laskoski、Arianna Neal、Mollie B. Schear、Teddy M. Keller、Holly L. Ricks-Laskoski、Andrew P. Saab

  DOI：10.1002/pola.27659

  日期：2015.9.15

  A versatile synthetic method has been developed for oligomeric aliphatic–aromatic ether containing phthalonitrile (PN) resins and applied to the preparation of three unique resin systems. The oligomeric PN monomers were prepared from the reaction of an excess amount of bisphenol A with a dihalo‐aliphatic containing compound in the presence of K2CO3 in dimethylsulfoxide, followed by end‐capping with

  已开发出一种通用的合成方法，用于含脂族-芳族醚的低聚邻苯二甲腈（PN）树脂，并已用于制备三种独特的树脂体系。低聚PN单体是在K 2 CO 3存在下，由过量的双酚A与含二卤代脂肪族化合物反应制得的在二甲基亚砜中，然后在两步一锅反应中用4-硝基邻苯二甲腈封端。这些PN树脂体系显示出优异的粘度，可在热固化后成型各种成型制品，以生成交联聚合物。与全芳香族骨架相比，这些聚合物具有更高的机械柔韧性，同时仍保持良好的热稳定性，介电性能和低吸水率。©2015 Wiley Periodicals，Inc. J. Polym。科学，A部分：Polym。化学 2015年，53，2186年至2191年
• Novel photosensitive bilayer composition
  申请人：Foster Patrick

  公开号：US20050042542A1

  公开（公告）日：2005-02-24

  Polymers and co-polymers having monomeric units formed by the polymerization of monomers of the Structure I where R 1 is a moiety containing an ethylenically unsaturated polymerizable group, R 2 is a C 1 -C 3 alkylene group, and R 3 is a C 1-10 linear or cyclic alkyl group, a C 6-10 aromatic or substituted aromatic group, a C 1-8 alkoxy methyl, or a C 1-8 alkoxy ethyl group, are useful as binder resins for photosensitive compositions, and processes for photolithography in the production of semiconductor devices and materials.

  具有由结构I单体聚合形成的单体单元的高分子和共聚物，其中R1是含有乙烯基不饱和可聚合基团的基团，R2是C1-C3烷基基团，R3是C1-10线性或环烷基团，C6-10芳香或取代芳香基团，C1-8烷氧甲基或C1-8烷氧乙基基团，可用作感光组合物的粘合剂树脂，以及在半导体器件和材料的制造中用于光刻工艺的过程。
• Photosensitive bilayer composition
  申请人：Foster Patrick

  公开号：US06929897B2

  公开（公告）日：2005-08-16

  Polymers and co-polymers having monomeric units formed by the polymerization of monomers of the Structure I where R 1 is a moiety containing an ethylenically unsaturated polymerizable group, R 2 is a C 1 -C 3 alkylene group, and R 3 is a C 1-10 linear or cyclic alkyl group, a C 6-10 aromatic or substituted aromatic group, a C 1-8 alkoxy methyl, or a C 1-8 alkoxy ethyl group, are useful as binder resins for photosensitive compositions, and processes for photolithography in the production of semiconductor devices and materials.

  具有结构I单体单元聚合形成的聚合物和共聚物，其中R1是含有乙烯基不饱和可聚合基团的基团，R2是C1-C3烷基基团，R3是C1-10线性或环烷基团，C6-10芳香或取代芳香基团，C1-8甲氧基甲基或C1-8甲氧基乙基基团，可用作光敏组合物的粘合剂树脂，并用于半导体器件和材料的光刻工艺。
• SYNTHESIS AND POLYMERIZATION OF OLIGOMERIC ALIPHATIC-AROMATIC BASED PHTHALONITRILES
  申请人：The Government of the United States of America, as represented by the Secretary of the Navy

  公开号：US20160168326A1

  公开（公告）日：2016-06-16

  A phthalonitrile compound having the formula below. The value n is a positive integer. Each R has a hydrocarbon chain optionally having —O— or —SiR′ 2 —O—. Each R′ is an aliphatic group. Each Ar is an aromatic group with the proviso that Ar contains at least two aromatic rings when n is 1 and R is an alkylene group. A method of: reacting an excess of a dihydroxyaromatic compound with a dihalocompound to form an oligomer; and reacting the oligomer with 4-nitrophthalonitrile to form the phthalonitrile compound, where Ar is an aromatic group.

  化合物的化学式如下，其中n为正整数。每个R具有一个碳氢链，可选择具有—O—或—SiR′2—O—。每个R′是一个脂肪基团。每个Ar是一个芳香族基团，条件是当n为1且R为烷基时，Ar至少包含两个芳香环。一种方法是：将过量的二羟基芳香化合物与二卤化合物反应形成寡聚物；然后将寡聚物与4-硝基邻苯二腈反应形成邻苯二腈化合物，其中Ar是一个芳香族基团。
• Synthesis and polymerization of oligomeric aliphatic-aromatic based phthalonitriles
  申请人：The United States of America, as represented by the Secretary of the Navy

  公开号：US09394404B2

  公开（公告）日：2016-07-19

  A phthalonitrile compound having the formula below. The value n is a positive integer. Each R has a hydrocarbon chain optionally having —O— or —SiR′2—O—. Each R′ is an aliphatic group. Each Ar is an aromatic group with the proviso that Ar contains at least two aromatic rings when n is 1 and R is an alkylene group. A method of: reacting an excess of a dihydroxyaromatic compound with a dihalocompound to form an oligomer; and reacting the oligomer with 4-nitrophthalonitrile to form the phthalonitrile compound, where Ar is an aromatic group.

  具有以下公式的邻苯二腈化合物。值n是正整数。每个R具有一个碳氢链，可以选择具有—O—或—SiR′2—O—。每个R′都是脂肪基。每个Ar都是芳香基，前提是当n为1且R为烷基时，Ar至少包含两个芳香环。一种方法：用过量的二羟基芳香化合物与二卤化合物反应形成寡聚物;然后用4-硝基邻苯二腈与寡聚物反应形成邻苯二腈化合物，其中Ar为芳香基。