chloro lead | 13931-84-5

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属盐
• 英文名称: chloro lead
• 英文别名: Chloro-plumbane；chlorolead
• CAS: 13931-84-5
• 化学式: ClPb
• 分子量: 242.653
• InChiKey: GACNLEQHDKHHQR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.31
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  lead 在 氯 作用下， 以 gaseous matrix 为溶剂， 生成 chloro lead
  参考文献：
  名称：

  高温下 Pb 与 N2O、Cl2、HCl 和 O2 反应的动力学

  摘要：

  基态铅原子的标题反应已在 HTFFR（高温快流反应器）中在 10-150 mbar 范围内的压力下进行了单独研究。铅消耗率系数...

  DOI：

  10.1021/jp000209z

文献信息

• Laser fluorescence study of the Pb+F₂, Cl₂ reactions: Internal state distribution of the PbCl product and radiative lifetimes of PbF(<i>A</i>,<i>B</i>) and PbCl(<i>A</i>)
  作者：Jing Chen、Paul J. Dagdigian

  DOI：10.1063/1.462189

  日期：1992.1.15

  The reactions of Pb atoms with molecular reagents F2 and Cl2 have been studied in a molecular beam apparatus by laser fluorescence detection of PbF and PbCl products. The experiments were performed in a beam-gas configuration under single-collision conditions. The PbCl product from Pb+Cl2 was observed in the vibrational levels v≤17 of the ground X1 electronic state. The PbCl product vibrational state distribution was derived; the average vibrational excitation was found to be 21% of the total available energy. For Pb+F2, PbF(X1) product was detected in only the v=0 and 1 vibrational levels, and the rovibrational state distribution could be characterized by a 300 K Boltzmann distribution. By modulating the Pb beam, it was concluded that this observed product was an artifact and did not arise from bimolecular gas-phase collisions. The radiative lifetimes of the PbF(A,B) and PbCl(A) states were also measured and were found to equal 4.9±0.3 μs, &lt;10 ns, and 1.14±0.06 μs, respectively, averaged over the observed vibrational levels.