mercury iodide bromide | 13444-76-3

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: mercury iodide bromide
• 英文别名: Mercury bromide iodide；bromo(iodo)mercury
• CAS: 13444-76-3
• 化学式: BrHgI
• 分子量: 407.399
• InChiKey: WWWSJCXNNVUYBN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -5.99
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  氢碘酸 、 溴化汞苯 以 二氯甲烷 为溶剂， 生成 mercury iodide bromide
  参考文献：
  名称：

  Boev, V. I., Journal of general chemistry of the USSR, 1992, vol. 62, p. 1095 - 1102

  摘要：

  DOI：

文献信息

• Solid State Reaction between CuI and HgClBr: Relevance of Electrical Resistivity Measurements in the Study of Solid-Solid Reactions
  作者：Saba Beg、Afaq Ahmad

  DOI：10.1006/jssc.1993.1200

  日期：1993.7

  The reaction between CuI and HgClBr in the solid state has been studied by resistivity measurements, X-ray diffraction, and chemical analysis. The reaction occurs differently at different molar ratios. The kinetics of the reaction has been studied by a visual technique. The reaction follows the usual rate law, Xπ = kt. The k's show the Arrhenius dependence. The activation energy, 43.30 ± 0.53 kJ/mol

  通过电阻率测量，X射线衍射和化学分析研究了CuI和HgClBr在固态下的反应。反应以不同的摩尔比不同地发生。已经通过视觉技术研究了反应的动力学。将反应遵循通常速率定律，X π =克拉。所述ķ的显示阿列纽斯依赖性。通过最小二乘拟合计算的活化能为43.30±0.53 kJ / mol，表明该反应受扩散控制，并通过HgClBr的气相扩散进行。
• HgBrI: A promising nonlinear optical material in IR region
  作者：Qi Wu、Yanjun Li、Huaichuan Chen、Kui Jiang、Hua Li、Cheng Zhong、Xingguo Chen、Jingui Qin

  DOI：10.1016/j.inoche.2013.04.034

  日期：2013.8

  This paper reports the second-order nonlinear optical (NLO) property of HgBrI for the first time. The compound was re-synthesized with a new synthetic method by combining the individual solution of stoichiometric amounts of HgBr2 and I-2 in acetone. The compound exhibits a strong phase-matchable second harmonic generation (SHG) property about 1.4 times stronger than KTiOPO4 (KTP) based on the powder SHG measurement. It also shows wide transparency in the infrared region from 0.46 to 40 mu m and good thermal stability with decomposition temperature at about 200 degrees C. All these properties indicate that HgBrI is a promising new candidate for NLO materials in the IR region. (c) 2013 Elsevier B.V. All rights reserved.