1,2-phenylenedimercury dichloride | 35099-05-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: 1,2-phenylenedimercury dichloride
• 英文别名: o-phenylene-bis-mercury chloride；di(chloromercurio)benzene
• CAS: 35099-05-9
• 化学式: C₆H₄Cl₂Hg₂
• 分子量: 548.184
• InChiKey: IIZASPXBQGIGSC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -4.57
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-phenylenedimercury dichloride 以 xylene 为溶剂， 生成 9,10-diethyl-9,10-dihydro-9,10-digallaanthracene(py)2
  参考文献：
  名称：

  Methyl or ethyl makes the difference: Synthesis and solid-state structure of 9,10-dialkyl-9,10-dihydro-9,10-digallaanthracenes

  摘要：

  The donor-free 9, 10-dialkyl-9, 10-dihydro-9, 10-digallaanthracenes 1 (alkyl: methyl) and 2 (alkyl: ethyl) were prepared by reaction of 1,2-di(chloromercurio)benzene with the corresponding trialkylgallium. and isolated as colourless air- and moisture sensitive crystalline compounds. In the solid-state structure of 1, two slightly different monomers 1A and 1B are found, which form a dimer 1A and 1B held together by "medium" strong gallium arene pi-interactions. Further weak pi-interactions between 1A and 1A and 1B and 1B constitute a one-dimensional coordination polymer containing strands of the composition [center dot center dot center dot(1A center dot center dot center dot 1B)center dot center dot center dot(1B center dot center dot center dot 1A)center dot center dot center dot](n). In contrast, compound 2 crystallizes in the form of distinct molecular units without any further intermolecular pi-interactions. The molecular units possess D-2d symmetry and are built by strong n-interactions between two digallaanthracene monomers. Two symmetrical aryl group bridges between two gallium atoms are observed for the first time in the subunits of 2. By addition of a Lewisbase (THF, Pyridine) to 2, a monomeric planar digallaanthracene framework is restored, as proven by an X-ray crystal structure analysis of 2 center dot 2Py. The different structures of 1 and 2 are explained on the basis of steric effects. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.04.024
• 作为产物：
  描述：

  dichloro-1,2-phenylenedimercury dimethylformamide 1:1 complex 以 neat (no solvent, solid phase) 为溶剂， 生成 1,2-phenylenedimercury dichloride
  参考文献：
  名称：

  多齿路易斯酸。二氯（1,2-亚苯基）二汞与二甲基甲酰胺的1：1配合物的晶体结构

  摘要：

  DOI：

  10.1021/om00144a028

文献信息

• Some reactions of phenylene-and polyphenylene-mercurials
  作者：A.G. Massey、N.A.A. Al-Jabar、R.E. Humphries、G.B. Deacon

  DOI：10.1016/0022-328x(86)82072-1

  日期：1986.11
• Multidentate Lewis acids. Reduction of thioketones in the presence of organomercury trifluoroacetates
  作者：James D. Wuest、Boulos Zacharie

  DOI：10.1021/ja00307a058

  日期：1985.10
• Wittig, G.; Bickelhaupt, F., Chemische Berichte, 1958, vol. 91, p. 883 - 894
  作者：Wittig, G.、Bickelhaupt, F.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Hg: MVol.B2, 109, page 625 - 628
  作者：

  DOI：——

  日期：——
• Multidentate Lewis acids. Halide complexes of 1,2-phenylenedimercury dihalides
  作者：James D. Wuest、Boulos Zacharie

  DOI：10.1021/om00121a043

  日期：1985.2