cobalt(II) ethoxide | 19330-29-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: cobalt(II) ethoxide
• 英文别名: cobalt ethoxide；cobalt diethylate；Einecs 242-967-3；cobalt(2+);ethanolate
• CAS: 19330-29-1
• 化学式: C₄H₁₀CoO₂
• 分子量: 149.115
• InChiKey: YJGIHGIKGWSVKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.64
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  cobalt(II) ethoxide 、 triethoxyantimony 以 甲苯 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  On the formation of M2+ -Sb3+ -alkoxide precursors and sol-gel processing of M-Sb oxides with M = Cr, Mn, Fe, Co, Ni, Cu and Zn

  摘要：

  Binary alkoxide complexes of compositions close to MSb(OEt)5, with M = Mn, Fe, Co and Ni, have been prepared and characterized by their i.r. and u.v.-VIS spectra, while Cr, Cu and Zn do not form similar ethoxide complexes with Sb(OEt)3. The Mn and Fe complexes must be prepared in inert atmosphere as they are very easily oxidized. The Fe complex is metastable and decomposes within a few hours. The Co complex can only be prepared in the presence of acetonitrile. X-ray amorphous gels were formed upon hydrolysis of solutions containing M to Sb species in the ratio 1:2 for M = Mn, Fe, Co and Ni. The gels consisted of agglomerated particles of sizes from 75 to 300 nm. The decomposition of the gels in air and in nitrogen has been monitored by means of thermogravimetric measurements. Samples of heated gels were quenched from various temperatures in the region 50-950-degrees-C, and the formed oxides were characterized by their X-ray powder patterns and by their infrared spectra. At 950-degrees-C MSb2O6 was formed in air, while in nitrogen MSb2O4 (M = Mn, Co and Ni) was formed at intermediate temperatures. At higher temperatures the latter compound decomposed and Sb2O3 sublimated.

  DOI：

  10.1007/bf00542925
• 作为产物：
  描述：

  钴 在 乙醇 作用下， 以 乙醇 为溶剂， 以84.7%的产率得到cobalt(II) ethoxide
  参考文献：
  名称：

  Bukhtiarov, A. V.; Rodnikov, I. A.; Zinov'eva, S. A., Journal of general chemistry of the USSR, 1990, vol. 60, p. 1192 - 1195

  摘要：

  DOI：

文献信息

• The preparation of finely divided metal powders and transition metal complexes using “organically solvated” magnesium
  作者：Helmut Bönnemann、Borislav Bogdanović、Rainer Brinkmann、Bernd Spliethoff、Da-Wei He

  DOI：10.1016/0022-328x(93)83004-f

  日期：1993.6

  Mg★ is an excellent in situ reducing agent for transition metal salts, giving highly reactive metal powders of Groups 8–12. In the presence of electron donor ligands, this reduction provides a useful one-step route to organotransition metal complexes. The application of 35 kHz ultrasound during the reaction improves the dispersity of the metal powders and enhances the yields of the complexes.

  用少量蒽在THF中处理市售镁粉会生成高活性形式的镁（Mg★）。Mg★是一种出色的过渡金属盐原位还原剂，可产生8-12组的高反应性金属粉末。在电子给体配体的存在下，这种还原为有机过渡金属配合物提供了有用的一步法。反应过程中施加35 kHz超声波可改善金属粉末的分散性，并提高配合物的收率。
• Funaioli, Tiziana; Biagini, Paolo; Zanazzi, Pier Francesco, Gazzetta Chimica Italiana, 1991, vol. 121, p. 321 - 324
  作者：Funaioli, Tiziana、Biagini, Paolo、Zanazzi, Pier Francesco、Fachinetti, Guiseppe

  DOI：——

  日期：——