dibutylphosphinous acid | 50602-70-5

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: dibutylphosphinous acid
• CAS: 50602-70-5
• 化学式: C₈H₁₉OP
• 分子量: 162.212
• InChiKey: FOSKLGIMCJXUFR-UHFFFAOYSA-N

物化性质

• 熔点：
  58-60 °C(Solv: ligroine (8032-32-4))
• 沸点：
  169-172 °C(Press: 13 Torr)
• 密度：
  1.0130 g/cm3(Temp: 420 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  dibutylphosphinous acid 在 caesium carbonate 、 potassium hydroxide 作用下， 以 1,4-二氧六环 、 水 、 二甲基亚砜 为溶剂， 反应 6.0h， 生成 (oxybis(methylene))bis(di-n-butylphosphinoxide)
  参考文献：
  名称：

  相转移催化条件下含磷配位化合物的合成-基于二苯基和二丁基磷酸甲醇的二甘醇酰胺的类似物

  摘要：

  一种方便的制备含磷豆荚的方法R 2 P（O）CH 2 OCH 2 X，其中X = C（O）NBu 2；P（O）R' 2，R = R'=苯基，卜，R =苯基，R'=卜经由铯的存在下，相转移条件下的phosphorylmethanols OH-烷基化2 CO 3被开发。氨基甲酰基取代的二甲醚是通过将磷酰基甲醇转化为磷酰基甲氧基乙酸，然后进行酰胺化反应而合成的。在Cs 2 CO 3存在下，使磷酰基甲醇与甲苯磺酰氯反应，得到对称的双磷酰基取代的二甲醚。在Cs 2 CO 3存在下不对称取代醚的合成由于甲苯磺酸磷酰基甲基酯的酯交换反应而复杂化，导致形成对称的副产物二甲醚。

  DOI：

  10.1134/s107036321809013x
• 作为产物：
  描述：

  dibutyl(α-mercapto-α-methylbenzyl)phosphine oxide 生成 dibutylphosphinous acid
  参考文献：
  名称：

  ZIMIN, M. G.;BURILOV, A. R.;ISLAMOV, R. G.;PUDOVIK, A. N., ZH. OBSHCH. XIMII, 1983, 53, N 1, 46-55

  摘要：

  DOI：
• 作为试剂：
  描述：

  1,2-二异硫氰酸亚苯酯 在 dibutylphosphinous acid 作用下， 以 乙醚 为溶剂， 以30%的产率得到1-<(dibutylphosphinyl)thiocarbonyl>-2-benzamidazolinethione
  参考文献：
  名称：

  Zimin, M. G.; Mironov, A. V.; Cherkasov, R. A., Journal of general chemistry of the USSR, 1985, vol. 55, # 2, p. 400 - 401

  摘要：

  DOI：

文献信息

• Guanidine Compound and Asymmetric Reaction Using the Same
  申请人：Terada Masahiro

  公开号：US20080154036A1

  公开（公告）日：2008-06-26

  A guanidine compound having a biaryl skeleton represented by the following formula (1), which is useful as a catalyst for various asymmetric reactions. (wherein R 1 , R 2 and R 3 each independently represent a hydrogen atom, a hydrocarbon group optionally having substituent(s), or a heterocyclic group optionally having substituent(s); R 4 to R 15 each independently represent a hydrogen atom, a hydrocarbon group optionally having substituent(s), a heterocyclic group optionally having substituent(s), a hydroxy group, an alkoxy group optionally having substituent(s), an aryloxy group optionally having substituent(s), an acyl group, an alkoxycarbonyl group optionally having substituent(s), an aryloxycarbonyl group optionally having substituent(s), a carbamoyl group optionally having substituent(s), an alkylthiocarbonyl group optionally having substituent(s), an arylthiocarbonyl group optionally having substituent(s), a carboxyl group, an alkylthio group optionally having substituent(s), an arylthio group optionally having substituent(s), an amino group or a substituted amino group, or a substituted silyl group; or in any combination of R 1 to R 15 , these substituents may be taken together to form a ring; and X 1 to X 8 represent a hydrogen atom or a nitrogen atom, provided that, in the case of a nitrogen atom, there is no substituent on X 1 to X 8 .

  具有以下式（1）表示的双芳基骨架的胍啉化合物，可用作各种不对称反应的催化剂。（其中，R1、R2和R3分别独立表示氢原子，可选地具有取代基的烃基或可选地具有取代基的杂环基；R4到R15独立地表示氢原子，可选地具有取代基的烃基，可选地具有取代基的杂环基，羟基，可选地具有取代基的烷氧基，可选地具有取代基的芳基氧基，酰基，可选地具有取代基的烷氧羰基，可选地具有取代基的芳基氧羰基，可选地具有取代基的氨基甲酰基，可选地具有取代基的硫代氨基甲酰基，可选地具有取代基的硫代芳基氨基甲酰基，羧基，可选地具有取代基的烷硫基，可选地具有取代基的芳基硫基，氨基或取代氨基，或取代硅基；或在R1到R15的任何组合中，这些取代基可结合在一起形成环；X1到X8表示氢原子或氮原子，前提是，在氮原子的情况下，X1到X8上没有取代基。
• Polyester production method, polyester composition, and polyester fiber
  申请人：——

  公开号：US20040266978A1

  公开（公告）日：2004-12-30

  In a polyester production method, a titanium compound having a radical selected from a carbonyl group, a carboxyl group, or an ester group, and a phosphorous compound having a structure illustrated in Formula (I), are added. 1 This yields a polyester composition which does not exhibit increased filter pressure when forming, which has excellent filament and film forming properties, and which has a polymer color tone superb to that of conventional products.

  在一种聚酯生产方法中，添加一种具有来自羰基团、羧基团或酯基团的基团的钛化合物和一种具有如公式（I）所示结构的磷化合物。这产生了一种聚酯组合物，其在成型时不会表现出增加的过滤器压力，具有优异的纤维和薄膜成型性能，并且具有比传统产品更好的聚合物颜色色调。
• Photoredox-Catalyzed Selective α-Scission of PR₃–OH Radicals to Access Hydroalkylation of Alkenes
  作者：Zhen-Zhen Xie、Zi-Hao Liao、Yu Zheng、Chu-Ping Yuan、Jian-Ping Guan、Ming-Zhi Li、Ke-Yi Deng、Hao-Yue Xiang、Kai Chen、Hua Yang

  DOI：10.1021/acs.orglett.3c03632

  日期：2023.12.22

  Photoinduced generation of phosphoranyl radicals offers a versatile strategy to access a variety of synthetically valuable radicals. A long-standing challenge remains in the regulation of phosphoranyl radical to undergo α-scission pathway, although the β-scission mode has been intensively studied. We herein developed an unprecedented protocol for selective α-scission of the P(OH)R3 radical intermediate

  光诱导产生正膦基自由基提供了一种通用策略来获取各种具有合成价值的自由基。尽管β-断裂模式已被深入研究，但调节正膦基自由基进行α-断裂途径仍然是一个长期存在的挑战。我们在此开发了一种前所未有的方案，用于在光催化条件下选择性 α-裂解 P(OH)R 3自由基中间体。这种通过 P(OH)R 3自由基的 α-断裂实现的有效 P-C 键断裂已成功用于烯烃的烷基化/氟烷基化。
• Solid catalyst component for alpha-olefin polymerization and process for producing the same
  申请人：Chisso Corporation

  公开号：EP0229413A1

  公开（公告）日：1987-07-22

  A solid catalyst component which can produce a-olefin polymers having a high stereoregularity and a good powder fluidity, stably and with a good efficiency in gas phase polymerization, particularly in gas phase copolymerization, a catalyst for a-olefin polymerization using the above solid catalyst component and a process for producing the above catalyst component, are provided, which solid catalyst component is characterized in that it contains titanium as an active ingredient and is in the form of hollow fine particles, and which process is characterized by adding a reaction product (I) of an organoaluminum compound (A) with an electron donor (B,) to TiCℓ4 and reacting these under agitation in a baffle ratio of 0.35 or less with a power required for agitation of 2.50 KW/m3 or less at a temperature of 0° to 70°C for a period of I to 10 hours and further reacting an electron donor (B2) and an electron acceptor (E) with the resulting solid product (II) to obtain a solid product (III) i.e. the solid catalyst component.

  本发明提供了一种在气相聚合（尤其是气相共聚）中能稳定、高效地生产出立体规整度高、粉末流动性好的 a- 烯烃聚合物的固体催化剂组分、使用上述固体催化剂组分的 a- 烯烃聚合催化剂以及生产上述催化剂组分的工艺、 其中固体催化剂组分的特点是含有钛作为活性成分，并呈中空细颗粒状，以及 该工艺的特征在于，将有机铝化合物（A）与电子供体（B,）的反应产物（I）加入到 TiCℓ4 中，并在 0.35 或更小的挡板比、搅拌所需功率为 2.50 KW/m3或更低，温度为0°至70°C，反应时间为I至10小时，并进一步将电子供体(B2)和电子受体(E)与所得固体产物(II)反应，以获得固体产物(III)，即固体催化剂组分。
• Kit of parts comprising a pressure-sensitive adhesive tape and a primer
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0889105A2

  公开（公告）日：1999-01-07

  A kit of parts comprising a structural hybrid pressure-sensitive adhesive tape and a primer, the structural hybrid pressure-sensitive adhesive tape comprising at least one structural hybrid pressure-sensitive adhesive layer with at least one exposed surface and, optionally, a backing. The structural hybrid pressure-sensitive adhesive comprises a thermosettable polymer component, a thermoplastic polymer component, and an effective amount of a heat-activatable hardener component and/or a photoinitiator component to cure the thermosettable polymer component. The primer comprises one or more silane, titanate, aluminum and/or zircoaluminate coupling agents which are optionally dissolved in a volatile inert organic solvent. Primer compositions and methods for preparing assemblies having two substrates are also disclosed.

  一种由结构混合压敏胶带和底漆组成的部件套件，结构混合压敏胶带包括至少一个具有至少一个暴露表面的结构混合压敏胶层，以及可选的背衬。结构杂化压敏胶包括热固性聚合物成分、热塑性聚合物成分和有效量的热激活固化剂成分和/或光引发剂成分，以固化热固性聚合物成分。底漆包括一种或多种硅烷、钛酸酯、铝和/或锆铝酸酯偶联剂，这些偶联剂可选择溶解在挥发性惰性有机溶剂中。此外，还公开了用于制备具有两种基底的组件的底漆组合物和方法。