tetrakis(trimethylsilyl)germanium | 19372-30-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: tetrakis(trimethylsilyl)germanium
• 英文别名: tetrakis(trimethylsilyl)germane；Tetrakis-trimethylsilyl-german
• CAS: 19372-30-6
• 化学式: C₁₂H₃₆GeSi₄
• 分子量: 365.35
• InChiKey: XABIPIGJPDTSBJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  17.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  tetrakis(trimethylsilyl)germanium 以 正己烷 为溶剂， 反应 3.5h， 生成 1,1,1,4,4,4-Hexakis(trimethylsilyl)-2,2,3,3-tetrachlorotetragermane
  参考文献：
  名称：

  “Donor–Acceptor” Oligogermanes: Synthesis, Structure, and Electronic Properties

  摘要：

  A series of oligogermanes, (Me3Si)(3)GeGeCl3, (C6F5)(3)GeGePh3, (C6F5)(3)GeGe(p-Tol)(3), and (C6F5)(2)Ge[Ge(p-Tol)(3)](2), containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these "donor-acceptor" oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

  DOI：

  10.1021/om4008218
• 作为产物：
  描述：

  tris(trimethylsilyl)germyllithium*2.5THF 以 乙醚 为溶剂， 生成 tetrakis(trimethylsilyl)germanium
  参考文献：
  名称：

  Preparation and structural characterization of trimethylsilyl-substituted germylzinc halides, (Me3Si)3GeZnX (X=Cl, Br, and I) and silylzinc chloride, R(Me3Si)2SiZnCl (R=SiMe3 and Ph)

  摘要：

  The trimethylsilyl-substituted germylzine halides, (Me3Si)(3)GeZnX (X = Cl, Br, and 1), and silylzinc chlorides, R(Me3Si)(2)SiZnCl (R = SiMe3, Ph), have been prepared and their molecular structures have been full determined by spectroscopic and single-crystal Xray diffraction methods. The germylzinc halides and silylzinc chlorides have dimeric structures consisting of two mu-halogen atoms. The reactivity of germylzinc chloride with substrates is also examined. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00148-7

文献信息

• β-Amino- and Alkoxy-Substituted Disilanides
  作者：Istvan Balatoni、Johann Hlina、Rainer Zitz、Alexander Pöcheim、Judith Baumgartner、Christoph Marschner

  DOI：10.3390/molecules24213823

  日期：——

  synthesis and properties of β-fluoro- and chlorodisilanides. The reaction of the functionalized neopentasilanes (Me3Si)3SiSiPh2NEt2 and (Me3Si)3SiSiMe2OMe with KOtBu in the presence of 18-crown-6 provided access to structurally related β-alkoxy- and amino-substituted disilanides. The obtained Et2NPh2Si(Me3Si)2SiK·18-crown-6 was converted to a magnesium silanide and further on to Et2NPh2Si(Me3Si)2Si-substituted

  我们最近对二硅烯的形式卤化物加合物的研究导致了对β-氟代和氯代二硅烷的合成和性质的研究。在 18-crown-6 存在下，官能化新戊硅烷 (Me3Si)3SiSiPh2NEt2 和 (Me3Si)3SiSiMe2OMe 与 KOtBu 的反应提供了结构相关的 β-烷氧基和氨基取代的二硅烷化物。将获得的Et 2 NPh 2 Si(Me 3 Si) 2 SiK·18-crown-6转化为硅烷化镁，并进一步转化为Et 2 NPh 2 Si(Me 3 Si) 2 Si取代的二茂锆和二茂铪氯化物。此外，还以中等选择性制备了同时含有 Et2NPh2Si 和 FPh2Si 基团的硅烷化物。还可以得到类似的锗化物Et2NPh2Si(Me3Si)2GeK·18-crown-6。
• The reactions of germenes generated thermally from pivaloyl- and adamantoyltris(trimethylsilyl)germane with 1,3-butadienes
  作者：Akinobu Naka、Shinsuke Ueda、Mitsuo Ishikawa

  DOI：10.1016/j.jorganchem.2007.02.011

  日期：2007.5

  The thermolysis of pivaloyl- and adamantoyltris(trimethylsilyl)germane in the presence of 2,3-dimethyl- and 2,3-diphenyl-1,3-butadiene gave the respective adducts derived from [2+4] cycloaddition of the germenes with butadienes in good yields.

  在2,3-二甲基-和2,3-二苯基-1,3-丁二烯存在下，将新戊酰基-和金刚烷基三（三甲基甲硅烷基）锗烷热解，得到相应的加合物，所述加合物衍生自the烯与丁二烯的[2 + 4]环加成。丰产。
• Radical Cyclizations of Acylgermanes. New Reagent Equivalents of the Carbonyl Radical Acceptor Synthon
  作者：Dennis P. Curran、Ulf Diederichsen、Michael Palovich

  DOI：10.1021/ja970219m

  日期：1997.5.1

  varied over 2 orders of magnitude by changing the germanium substituents. Acyltriarylgermanes are among the best radical acceptors yet identified, and this quality makes them superior reagent equivalents of the carbonyl radical acceptor synthon. Parent cyclizations in the 4-exo and 7-exo modes fail. Attempted 3-exo cyclization results in a 1,2-acyl shift...

  报道了对酰基锗烷在自由基环化中作为受体的能力的深入研究。自由基添加到酰基锗烷上，所产生的 α-锗烷基烷氧基自由基的快速碎裂提供了酮和锗烷基。胚芽自由基依次通过加成或提取来传播链，因此反应通过单分子链转移 (UMCT) 过程发生。相比之下，酰基硅烷也起到自由基受体的作用，但它们不参与 UMCT 过程，因为“自由基-布鲁克”重排介入。5-exo 和 6-exo 模式中的环化显示出良好的范围，并且环化的速率常数可以通过改变锗取代基而变化超过 2 个数量级。酰基三芳基锗烷是目前已确定的最佳自由基受体之一，这种质量使它们成为羰基自由基受体合成子的优良试剂等价物。4-exo 和 7-exo 模式中的亲本环化失败。尝试 3-exo 环化导致 1,2-酰基转移...
• Structural Aspects of Trimethylsilylated Branched Group 14 Compounds
  作者：Judith Baumgartner、Roland Fischer、Jelena Fischer、Andreas Wallner、Christoph Marschner、Ulrich Flörke

  DOI：10.1021/om050835o

  日期：2005.12.1

  [(Me3Si)3X1X2(SiMe3)3] (X1, X2 = Si, Ge, or Sn) together with some related compounds bearing triisopropylsilyl or -stannyl groups are characterized by single-crystal X-ray crystallography. The structural data are compared to similar compounds already known. The interaction of silyl groups connected to different central atoms such as Si, Ge, and Sn is analyzed.

  一些新合成的类型为[（Me 3 Si）3 X 1 X 2（SiMe 3）3 ]（X 1，X 2 = Si，Ge或Sn）的化合物以及一些带有三异丙基甲硅烷基或-锡烷基的相关化合物。通过单晶X射线晶体学表征。将结构数据与已知的类似化合物进行比较。分析了连接到不同中心原子（例如Si，Ge和Sn）的甲硅烷基的相互作用。
• Synthesis of some tris(trimethylsilyl)germyl compounds
  作者：A.G. Brook、F. Abdesaken、H. Söllradl

  DOI：10.1016/0022-328x(86)84028-1

  日期：1986.1

  A variety of compounds containing the tris(trimethylsilyl)germyl group were prepared and characterized spectroscopically. Photolysis of adamantoyltris(trimethylsilyl)germane failed to yield the isomeric germene: in CCl4 the photolysis appeared to occur by a Norrish type 1 process.

  制备了多种含有三（三甲基甲硅烷基）锗烷基的化合物，并进行了光谱表征。金刚烷基三（三甲基甲硅烷基）锗烷的光解不能产生异构的胚芽烯：在CCl 4中，光解似乎是通过一种Norrish 1型过程发生的。