tetra(episulfide) | 893411-65-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫杂环丙烷
• 英文名称: tetra(episulfide)
• 英文别名: 2,2a(2)-[[2,2-Bis[(thiiranylmethoxy)methyl]-1,3-propanediyl]bis(oxymethylene)]bis[thiirane]；2-[[3-(thiiran-2-ylmethoxy)-2,2-bis(thiiran-2-ylmethoxymethyl)propoxy]methyl]thiirane
• CAS: 893411-65-9
• 化学式: C₁₇H₂₈O₄S₄
• 分子量: 424.671
• InChiKey: NADBOSDSDIWQFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  25
• 可旋转键数：
  16
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  138
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  N-哌嗪甲酸乙酯 、 tetra(episulfide) 以 甲醇 为溶剂， 反应 24.0h， 以60%的产率得到
  参考文献：
  名称：

  [EN] DENDRITIC POLYMERS WITH ENHANCED AMPLIFICATION AND INTERIOR FUNCTIONALITY
  [FR] POLYMERES DENDRITIQUES AVEC FONCTIONNALITE INTERIEURE ET AMPLIFICATION RENFORCEES

  摘要：

  公开号：

  WO2006115547A3
• 作为产物：
  描述：

  季戊四醇缩水甘油醚 在 LiBF₄ 、 硫脲 作用下， 以 水 、 乙腈 为溶剂， 以29%的产率得到tetra(episulfide)
  参考文献：
  名称：

  Dendritic polymers with enhanced amplification and interior functionality

  摘要：

  聚酯丙烯酸酯和聚酯/环氧树脂树状分子。这些材料可以通过利用所谓的“立体诱导的化学计量原则”来合成。树状分子的制备是通过将前驱氨基/多氨基功能核心材料与各种支链细胞试剂反应而进行的。支链细胞试剂在尺寸上大于氨基/多氨基引发剂核心，当反应时，可以一步直接产生一代树状分子。还有一种方法可以稳定树状分子，即将树状分子与表面活性分子反应，以平息树状分子上的活性基团。

  公开号：

  US07981444B2

文献信息

• DENDRITIC POLYMERS WITH ENHANCED AMPLIFICATION AND INTERIOR FUNCTIONALITY
  申请人：Dendritic Nanotechnologies, Inc.

  公开号：EP1737899B1

  公开（公告）日：2015-07-08
• Dendritic Polymers with Enhanced Amplification and Interior Functionality
  申请人：Tomalia A. Donald

  公开号：US20070244296A1

  公开（公告）日：2007-10-18

  Poly(ester-acrylate) and poly(ester/epoxide) dendrimers. These materials can be synthesized by utilizing the so-called “sterically induced stoichiometric” principles. The preparation of the dendrimers is carried out by reacting precursor amino/polyamino-functional core materials with various branch cell reagents. The branch cell reagents are dimensionally large, relative to the amino/polyamino-initiator core and when reacted, produce generation=1 dendrimers directly in one step. There is also a method by which the dendrimers can be stabilized and that method is the reaction of the dendrimers with surface reactive molecules to pacify the reactive groups on the dendrimers.
• Dendritic Polymers With Enhanced Amplification and Interior Functionality
  申请人：Tomalia A. Donald

  公开号：US20070298006A1

  公开（公告）日：2007-12-27

  Dendritic polymers with enhanced amplification and interior functionality are disclosed. These dendritic polymers are made by use of fast, reactive ring-opening chemistry (or other fast reactions) combined with the use of branch cell reagents in a controlled way to rapidly and precisely build dendritic structures, generation by generation, with cleaner chemistry, often single products, lower excesses of reagents, lower levels of dilution, higher capacity method, more easily scaled to commercial dimensions, new ranges of materials, and lower cost. The dendritic compositions prepared have novel internal functionality, greater stability (e.g., thermal stability and less or no reverse Michael's reaction), and reach encapsulation surface densities at lower generations. Unexpectedly, these reactions of polyfunctional branch cell reagents with polyfunctional cores do not create cross-linked materials. Such dendritic polymers are useful as demulsifiers for oil/water emulsions, wet strength agents in the manufacture of paper, proton scavengers, polymers, nanoscale monomers, calibration standards for electron microscopy, making size selective membranes, and agents for modifying viscosity in aqueous formulations such as paint. When these dendritic polymers have a carried material associated with their surface and/or interior, then these dendritic polymers have additional properties for carrying materials due to the unique characteristics of the dendritic polymer, such as for drug delivery, transfection, and diagnostics.
• US7985424B2
  申请人：——

  公开号：US7985424B2

  公开（公告）日：2011-07-26
• US7981444B2
  申请人：——

  公开号：US7981444B2

  公开（公告）日：2011-07-19