1,7-bis(trimethylsilylmethyldichlorostannyl)dipropyl ether | 653577-78-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,7-bis(trimethylsilylmethyldichlorostannyl)dipropyl ether
• CAS: 653577-78-7
• 化学式: C₁₄H₃₄Cl₄OSi₂Sn₂
• 分子量: 653.826
• InChiKey: PYNXLBBJNBKYPW-UHFFFAOYSA-J

物化性质

• 沸点：
  479.7±45.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -7.9
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,7-bis(trimethylsilylmethyldichlorostannyl)dipropyl ether 、 potassium hydroxide 以 水 、 甲苯 为溶剂， 以86%的产率得到1,7-bis(trimethylsilylmethyloxostannyl)dipropyl ether
  参考文献：
  名称：

  Synthesis and structure of an ether-bridged double ladder compound: potential in host–guest chemistry

  摘要：

  The synthesis of the first example of an organotin double ladder (6) containing a functional group within the spacer is reported. In the solid state, compound 6 shows an interlaminar cavity whose size and shape suggest the possibility of host-guest chemistry. Sn-119-NMR and ESMS show that compound 6 undergoes extensive dissociation in solution. ESMS of compound 6 to which have been added Li+, Na+, Mg2+ or Cu2+ show only minimal interaction. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.08.029
• 作为产物：
  描述：

  烯丙基醚 在 Pd(OH)2/C 、 KF 、 H₂O₂ 作用下， 以 四氢呋喃 、 二氯甲烷 、 氯仿 、 水 、 甲苯 为溶剂， 生成 1,7-bis(trimethylsilylmethyldichlorostannyl)dipropyl ether
  参考文献：
  名称：

  Synthesis and structure of an ether-bridged double ladder compound: potential in host–guest chemistry

  摘要：

  The synthesis of the first example of an organotin double ladder (6) containing a functional group within the spacer is reported. In the solid state, compound 6 shows an interlaminar cavity whose size and shape suggest the possibility of host-guest chemistry. Sn-119-NMR and ESMS show that compound 6 undergoes extensive dissociation in solution. ESMS of compound 6 to which have been added Li+, Na+, Mg2+ or Cu2+ show only minimal interaction. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.08.029

文献信息

• Synthesis and structure of an ether-bridged double ladder compound: potential in host–guest chemistry
  作者：Jens Beckmann、Dainis Dakternieks、Andrew Duthie、Fong Sheen Kuan、Edward R.T Tiekink

  DOI：10.1016/j.jorganchem.2003.08.029

  日期：2003.12

  The synthesis of the first example of an organotin double ladder (6) containing a functional group within the spacer is reported. In the solid state, compound 6 shows an interlaminar cavity whose size and shape suggest the possibility of host-guest chemistry. Sn-119-NMR and ESMS show that compound 6 undergoes extensive dissociation in solution. ESMS of compound 6 to which have been added Li+, Na+, Mg2+ or Cu2+ show only minimal interaction. (C) 2003 Elsevier B.V. All rights reserved.