10-(Triethoxysilyl)1,4,7-triazadekan | 4693-51-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 10-(Triethoxysilyl)1,4,7-triazadekan
• 英文别名: N~1~-(2-Aminoethyl)-N~2~-[3-(triethoxysilyl)propyl]ethane-1,2-diamine；N'-[2-(3-triethoxysilylpropylamino)ethyl]ethane-1,2-diamine
• CAS: 4693-51-0
• 化学式: C₁₃H₃₃N₃O₃Si
• 分子量: 307.509
• InChiKey: VNRDAMBPFDPXSM-UHFFFAOYSA-N

物化性质

• 沸点：
  155-157 °C(Press: 2 Torr)
• 密度：
  0.9845 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  0.56
• 重原子数：
  20
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  77.8
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  10-(Triethoxysilyl)1,4,7-triazadekan 、 双(二甲胺基)氯酸磷 在 三乙胺 作用下， 以 正己烷 为溶剂， 反应 4.0h， 生成 N,N',N'',N''-Tetrakis(bis(dimethylamido)phosphoryl)-3-[2-(2-aminoethylamino)-ethylamino]-propyltriethoxysilan
  参考文献：
  名称：

  Synthese und Einsatz von trägerfixierten Katalysatoren zur heterogen-katalysierten SiSi-Bindungsspaltung in Chlormethyldisilanen

  摘要：

  Lewis bases like bis(dimethylamide)phosphoryl compounds (2, 5-7), N-heterocycles (8 and 9) and N,N-dialkylamina-3-propylsilanes bearing alkoxy groups are grafted via siloxane bonds onto silica carriers. The preparation and characterisation of 5-9 are reported. The grafted bis(dimethylamide)phosphoryl compounds (2, 5-7) and N-heterocycles (8, 9) are efficient catalysts for the disproportionation of chloromethyldisilanes into chloromethyloligosilanes and chloromethylsilanes. Grafted N,N-dialkylamino-3-propylsilyl compounds heterogeneously catalyze the Si-Si bond cleavage of the disilanes with hydrogen chloride at 170 degrees C in excellent yields. A mixture of chloromethylmonosilanes is obtained. This reaction is also performed under pressure.

  DOI：

  10.1002/prac.19973390128
• 作为产物：
  描述：

  3-氯丙基三乙氧基硅烷 、 二乙烯三胺 生成 10-(Triethoxysilyl)1,4,7-triazadekan
  参考文献：
  名称：

  Losev,V.B.; Zhinkin,D.Ya., Journal of general chemistry of the USSR, 1969, vol. 39, p. 935 - 936

  摘要：

  DOI：

文献信息

• Losev,V.B.; Zhinkin,D.Ya., Journal of general chemistry of the USSR, 1969, vol. 39, p. 935 - 936
  作者：Losev,V.B.、Zhinkin,D.Ya.

  DOI：——

  日期：——
• Synthese und Einsatz von trägerfixierten Katalysatoren zur heterogen-katalysierten SiSi-Bindungsspaltung in Chlormethyldisilanen
  作者：Robin Richter、Norbert Schulze、Gerhard Roewer、Jens Albrecht

  DOI：10.1002/prac.19973390128

  日期：——

  Lewis bases like bis(dimethylamide)phosphoryl compounds (2, 5-7), N-heterocycles (8 and 9) and N,N-dialkylamina-3-propylsilanes bearing alkoxy groups are grafted via siloxane bonds onto silica carriers. The preparation and characterisation of 5-9 are reported. The grafted bis(dimethylamide)phosphoryl compounds (2, 5-7) and N-heterocycles (8, 9) are efficient catalysts for the disproportionation of chloromethyldisilanes into chloromethyloligosilanes and chloromethylsilanes. Grafted N,N-dialkylamino-3-propylsilyl compounds heterogeneously catalyze the Si-Si bond cleavage of the disilanes with hydrogen chloride at 170 degrees C in excellent yields. A mixture of chloromethylmonosilanes is obtained. This reaction is also performed under pressure.