申请人:SHIN-ETSU CHEMICAL CO., LTD.
公开号:EP0372996A2
公开(公告)日:1990-06-13
A method of preventing polymer scale deposition in a polymerization vessel during polymerization of a monomer having an ethylenically double bond, wherein said polymerization is carried out in a polymerization vessel of which the inner wall has been previously first coated with
(A) a coating solution comprising a condensate of an aromatic compound and at least one member selected from the group consisting of metal compounds and inorganic colloids, and the coating thus formed has been then coated with
(B) a coating solution comprising at least one member selected from the group consisting of anionic polymeric compounds, amphoteric polymeric compounds and hydroxyl group-containing polymeric compounds; and a polymerization vessel having a coating thus formed. According this method, polymer scale deposition on the inner wall, etc. of the polymerization vessel can be effectively prevented.
一种在具有乙烯双键的单体聚合过程中防止聚合物垢沉积在聚合容器中的方法,其中所述聚合是在聚合容器中进行的,聚合容器的内壁先前已先涂覆了以下涂层
(A) 由芳香族化合物的缩合物和至少一种选自金属化合物和无机胶体的成员组成的涂层溶液,然后在由此形成的涂层上涂覆以下物质
(B) 由至少一种选自阴离子高分子化合物、两性高分子化合物和含羟基高分子化合物组的成员组成的涂层溶液;以及具有由此形成的涂层的聚合容器。根据这种方法,可有效防止聚合物垢沉积在聚合容器的内壁等处。