dichloro-bis-(2-trichlorosilanyl-ethyl)-silane | 18142-65-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: dichloro-bis-(2-trichlorosilanyl-ethyl)-silane
• 英文别名: Dichlor-bis-(2-trichlorsilyl-aethyl)-silan；1,1,1,4,4,7,7,7-Octachlor-trisilyl-ethylen；Bis-(2-trichlorsilyl-ethyl)-dichlorsilan；1,1,1,4,4,7,7,7-Octachloro-1,4,7-trisilaheptane；trichloro-[2-[dichloro(2-trichlorosilylethyl)silyl]ethyl]silane
• CAS: 18142-65-9
• 化学式: C₄H₈Cl₈Si₃
• 分子量: 423.988
• InChiKey: LUIYTAGOZMVGSB-UHFFFAOYSA-N

物化性质

• 熔点：
  44-46 °C
• 沸点：
  154.5-156 °C(Press: 5 Torr)
• 密度：
  1.447±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.22
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  dichloro-bis-(2-trichlorosilanyl-ethyl)-silane 、 甲基溴化镁 生成 Bis-(2-trimethylsilyl-aethyl)-dimethyl-silan
  参考文献：
  名称：

  Mueller; Schnurrbusch, Chemische Berichte, 1958, vol. 91, p. 1805,1815

  摘要：

  DOI：
• 作为产物：
  描述：

  乙烯基三氯硅烷 在 dihydrogen hexachloroplatinate 、 二氯硅烷 作用下， 以 异丙醇 为溶剂， 190.0 ℃ 、1.52 MPa 条件下， 生成 dichloro-bis-(2-trichlorosilanyl-ethyl)-silane
  参考文献：
  名称：

  Odabashyan,G.V. et al., Doklady Chemistry, 1962, vol. 142, p. 70 - 73

  摘要：

  DOI：

文献信息

• Novel nanoparticle containing siloxane polymers
  申请人：Rantala Juha

  公开号：US20080188032A1

  公开（公告）日：2008-08-07

  A method of producing a polymer composition for semiconductor optoelectronics, comprising the steps of providing at least one type of disilane monomer which is homo- or copolymerized to form a (co)polymer and then combined with nanoparticles to provide a polymer composition. The nanoparticle containing composition has excellent properties with high refractive index or dielectric constant.

  一种用于制造半导体光电子聚合物组分的方法，包括以下步骤：提供至少一种二硅烷单体，该单体经过同聚或共聚形成（共）聚合物，然后与纳米颗粒结合以提供聚合物组分。含有纳米颗粒的组分具有高折射率或介电常数的优异性能。
• Organo functionalized silane monomers and siloxane polymers of the same
  申请人：Rantala T. Juha

  公开号：US20060293482A1

  公开（公告）日：2006-12-28

  A thin film comprising a composition obtained by polymerizing a monomer having the formula I: wherein: R 1 is a hydrolysable group, R 2 is an organic crosslinking group, a reactive cleaving group or a polarizability reducing organic group, and R 3 is a bridging linear or branched bivalent hydrocarbyl group to form a siloxane material. The organo-functionalized molecule is capable of further reacting in the matrix so as to undergo cross-linking, cleaving or combination of both. The present invention provides excellent chemical resistance and very low chemical adsorption behavior due to high cross-linking bridging group density.

  一种薄膜，包括由聚合式单体制备的组合物，该聚合式单体具有式I：其中：R1为可水解基团，R2为有机交联基团、反应性断裂基团或极化还原有机基团，而R3为桥联线性或分支二价碳氢基团，以形成硅氧烷材料。有机官能化分子能够在基质中进一步反应，以经历交联、断裂或两者的组合。本发明由于具有高交联桥联基团密度，提供了优异的化学抗性和非常低的化学吸附行为。
• Silane monomers and siloxane polymers for semiconductor optoelectronics
  申请人：Rantala T. Juha

  公开号：US20060293478A1

  公开（公告）日：2006-12-28

  A method for producing a polymer for semiconductor optoelectronics, comprising the steps of providing a monomer is produced having the formula: wherein: R 1 is a hydrolysable group R 2 is hydrogen, and R 3 is a bridging linear or branched bivalent hydrocarbyl group, said monomer being produced by hydrosilylation of the corresponding starting materials, and homo- or copolymerizing the monomer to produce a polymer.

  一种用于制备半导体光电聚合物的方法，包括以下步骤：提供一个具有以下公式的单体：其中：R1是可水解基团，R2是氢，R3是桥接的线性或分支双价烃基团，所述单体通过对应的起始材料进行氢硅烷化反应而制备，并通过均聚或共聚合成聚合物。
• Semiconductor optoelectronics devices
  申请人：Rantala Juha T.

  公开号：US20070284687A1

  公开（公告）日：2007-12-13

  A semiconductor device comprising a semiconductor substrate with a plurality of photo-diodes arranged in the semiconductor substrate with interconnect layers defining apertures at the photo-diodes and a first polymer which fills the gaps such as to cover the photo-diode. Further, layers of color filters are arranged on top the gap filling polymer layer opposite to the photo-diodes and a second polymer arranged on the interconnect layers covers and planarizes and passivates the color filter layers. On top of the planarizing polymer there is a plurality of micro-lenses opposite to the color filters, and a third polymer layer is deposited on the micro-lenses for passivating the micro-lenses. According to the invention the polymer materials are comprised of a siloxane polymer which gives thermally and mechanically stable, high index of refraction, dense dielectric films exhibiting high-cracking threshold, low pore volume and pore size.

  一种半导体器件，包括半导体基板，其中在半导体基板上排列有多个光电二极管，互连层在光电二极管处定义孔隙，并且第一聚合物填充间隙，以覆盖光电二极管。此外，颜色滤光片层排列在填充间隙的聚合物层的顶部，与光电二极管相对，第二聚合物排列在互连层上，覆盖、平整化和无源化颜色滤光片层。在平整化聚合物的顶部，有多个微透镜与颜色滤光片相对，第三聚合物层沉积在微透镜上，以无源化微透镜。根据本发明，聚合物材料由硅氧烷聚合物组成，可提供具有高折射率、密度介电膜、高热稳定性和机械稳定性的膜，具有高裂纹阈值、低孔隙体积和孔径。
• Nanoparticle containing siloxane polymers
  申请人：Silecs Oy

  公开号：US07833820B2

  公开（公告）日：2010-11-16

  A method of producing a polymer composition for semiconductor optoelectronics, comprising the steps of providing at least one type of disilane monomer which is homo- or copolymerized to form a (co)polymer and then combined with nanoparticles to provide a polymer composition. The nanoparticle containing composition has excellent properties with high refractive index or dielectric constant.

  一种用于制备半导体光电子聚合物组合物的方法，包括以下步骤：提供至少一种二硅烷单体，该单体通过同源或共聚反应形成（共）聚合物，然后与纳米颗粒结合形成聚合物组合物。该含纳米颗粒的组合物具有高折射率或介电常数等优异性能。