1,2-bis(tri-n-propylsilyl)ethane | 18643-01-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: 1,2-bis(tri-n-propylsilyl)ethane
• 英文别名: hexa-Si-propyl-Si,Si'-ethanediyl-bis-silane；Hexa-Si-propyl-Si,Si'-aethandiyl-bis-silan；1,2-Bis-tripropylsilyl-aethan；1-[Dipropyl-(2-tripropylsilanyl-ethyl)-silanyl]-propane；tripropyl(2-tripropylsilylethyl)silane
• CAS: 18643-01-1
• 化学式: C₂₀H₄₆Si₂
• 分子量: 342.756
• InChiKey: XRXDZGKZBDYCNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.34
• 重原子数：
  22
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三丙基氯硅烷 在 potassium hydroxide 、 lithium diisopropyl amide 作用下， 以 甲醇 、 乙腈 为溶剂， 反应 4.0h， 生成 1,2-bis(tri-n-propylsilyl)ethane
  参考文献：
  名称：

  Electrochemical Synthesis of 1,2-Disilylethanes from α-Silylacetic Acids

  摘要：

  The synthesis of 1,2-disilylethanes [R1R2R3Si-(CH2)(2)SiR1R2R3] is usually conducted by using noble metal reagents or catalysts. This work describes a new electrochemical synthetic method for their preparation in good yields by oxidation of alpha-silylacetic acids at Pt anodes (Kolbe electrolysis). Most of the reported synthesized 1,2-disilylethanes in this work are unknown.

  DOI：

  10.1021/jo200254z

文献信息

• Nametkin et al., Doklady Akademii Nauk SSSR, 1954, vol. 96, p. 1003,1004
  作者：Nametkin et al.

  DOI：——

  日期：——
• Electrochemical Synthesis of 1,2-Disilylethanes from α-Silylacetic Acids
  作者：Alex V. Shtelman、James Y. Becker

  DOI：10.1021/jo200254z

  日期：2011.6.3

  The synthesis of 1,2-disilylethanes [R1R2R3Si-(CH2)(2)SiR1R2R3] is usually conducted by using noble metal reagents or catalysts. This work describes a new electrochemical synthetic method for their preparation in good yields by oxidation of alpha-silylacetic acids at Pt anodes (Kolbe electrolysis). Most of the reported synthesized 1,2-disilylethanes in this work are unknown.