dimethylbis(4-pyridyl)silane | 251950-48-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: dimethylbis(4-pyridyl)silane
• 英文别名: Dimethyl(dipyridin-4-yl)silane
• CAS: 251950-48-8
• 化学式: C₁₂H₁₄N₂Si
• 分子量: 214.342
• InChiKey: WYIRRDDPHORLTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dimethylbis(4-pyridyl)silane 以 甲醇 、 乙醇 、 水 为溶剂， 反应 51.08h， 生成
  参考文献：
  名称：

  Insight into the crystallization process: relationships between crystal structures and properties of copper(ii) coordination polymers containing dimethylbis(4-pyridyl)silane

  摘要：

  进行了一项系统研究，探讨构建铜(II)配位聚合物的有利反应条件。将铜(II)溴化物与二甲基双(4-吡啶基)硅烷(L)进行多种反应，生成了两种骨架结构：一维环链和方形螺旋管。快速形成的条件产生一维环链，而缓慢形成的条件产生螺旋结构。显著条件依赖性结构的形成可以部分归因于溴化物阴离子的性质以及铜(II)阳离子周围的角应变。本文讨论了这些结构与物理化学性质（如阴离子可交换性、3,5-二叔丁基邻苯二酚的催化氧化和热性质）之间的关系。

  DOI：

  10.1039/c3ce40257f

文献信息

• Preparation and Solid-State Properties of Self-Assembled Dinuclear Platinum(II) and Palladium(II) Rhomboids from Carbon and Silicon Tectons
  作者：Marion Schmitz、Stefan Leininger、Jun Fan、Atta M. Arif、Peter J. Stang

  DOI：10.1021/om990567s

  日期：1999.11.1

  hitherto unknown bis(4-pyridyl)silanes 2a,b with bis(triethylphosphine)platinum and bis(triethylphosphine)palladium bistriflates 5a,b lead to the formation of new silicon-containing rhomboids 6a−d. In addition, a similar carbon analogue 7 was prepared by reaction of bispyridyl acetal 4 and bis(triethylphosphine)platinum bistriflate (5a). Surprisingly, reaction of the bis(4-pyridyl)ketone (3) and the platinum

  迄今未知的双（4-吡啶基）硅烷2a，b与双（三乙基膦）铂和双（三乙基膦）钯双三氟甲磺酸酯5a，b的自组装反应导致形成新的含硅菱形6a - d。另外，通过双吡啶基乙缩醛4和双（三乙基膦）铂二铋酸盐（5a）的反应制备了类似的碳类似物7。出乎意料的是，双（4-吡啶基）酮（3）与铂络合物5a的反应产生了类似的菱形10，由于酮的意外水合作用。解析了硅络合物6a及其碳类似物7的晶体结构，并将其与已知的含碳双核菱形进行了比较。另外，还通过X射线结构分析表征了双核双卟啉复合物8。还报告了电喷雾和FAB质谱数据，证实了所形成实体的双核性质。
• Synthesis, Structures, and Catalytic Properties of Ionic Metallacyclodimeric Palladium(II) Complexes
  作者：Sung Min Kim、Kyung Hwan Park、Haeri Lee、So Yun Moon、Ok-Sang Jung

  DOI：10.5012/bkcs.2012.33.12.4069

  日期：2012.12.20

  Metallacyclodimeric complexes of $[(Me_4en)Pd(L)]_2(ClO_4)_4$ ($Me_4en$ = N,N,N',N'-tetramethylethylenediamine; L = dimethylbis(4-pyridyl)silane (dmps), methylvinylbis(4-pyridyl)silane (mvps)) have been synthesized, and their structures have been characterized by X-ray single crystallography. The skeletal structures consist of one 20-membered metallamacrocycle, two 5-membered metallacycles, and four pyridyl groups. The local geometry around the palladium(II) ion approximates to a typical square planar arrangement with four nitrogen donors. Delicate difference in catalytic effects on hydrogenation was investigated based on the structure of catalyst and substrates.

  $[(Me_4en)Pd(L)]_2(ClO_4)_4$（$Me_4en$ = N,N,N',N'-四甲基乙二胺；L = 二甲基双(4-吡啶基)硅烷 (dmps)，甲基乙烯基双(4-吡啶基)硅烷 (mvps))已被合成，其结构已通过 X 射线单晶学进行了表征。它们的骨架结构由一个 20 元金属环、两个 5 元金属环和四个吡啶基组成。钯（II）离子周围的局部几何结构近似于典型的方形平面布置，有四个氮供体。根据催化剂和底物的结构，研究了氢化催化效果的微妙差异。
• Relationship between the Ratio of Ligand to Metal and the Coordinating Ability of Anions. Synthesis and Structural Properties of AgX-Bearing Bis(4-pyridyl)dimethylsilane (X^- = NO₂^-, NO₃^-, CF₃SO₃^-, and PF₆^-)
  作者：Jung Woon Lee、Eun Ae Kim、Yun Ju Kim、Young-A Lee、Youngshang Pak、Ok-Sang Jung

  DOI：10.1021/ic048537r

  日期：2005.5.1

  construction of a series of AgX complexes with bis(4-pyridyl)dimethylsilane (L) (X- = NO2-, NO3-, CF3SO3-, and PF6-) have been carried out. Formation of the skeletal bonds appears to be primarily associated with a suitable combination of bidentate N-donors of L and a variety of coordination geometries of Ag(I) ions. The L:Ag(I) ratios of the products are dependent on the nature of the polyatomic anions. The

  已经进行了阴离子对一系列具有双（4-吡啶基）二甲基硅烷（L）（X- = NO2-，NO3-，CF3SO3-和PF6-）的AgX配合物的分子结构的研究。骨架键的形成似乎主要与L的双齿N供体和Ag（I）离子的各种配位几何结构的适当组合有关。产物的L∶Ag（I）比取决于多原子阴离子的性质。获得了NO2-的1：1加合物Ag（I）-L，NO3-的3：4加合物，CF3SO3-的2：3加合物和PF6-的1：2加合物。观察到配体与金属的比例与阴离子的配位能力之间存在线性关系。[Ag（NO2）（L）]具有由双螺旋组成的独特片状结构，[Ag3（L）4]（NO3）3是由纳米管组成的2 nm厚的交织片状结构。
• A 20-Å-Thick Interwoven Sheet Consisting of Nanotubes
  作者：Ok-Sang Jung、Yun Ju Kim、Kwan Mook Kim、Young-A Lee

  DOI：10.1021/ja026774s

  日期：2002.7.1

  Slow diffusion of AgNO3 with Me2Si(4-Py)2 yields an interwoven 2-nm-thick sheet consisting of the building block [Ag3(Me2Si(4-Py)2)4](NO3)3.H2O. The interweaving induces unique nanotunnels with a 16 x 18 A2 cross section with a 7 x 8 A2 square pore. The anion NO3- of the skeletal sheet can be reversibly exchanged with appropriately sized anions without the collapse of its structural integrity. The compound has a melting point (140 degrees C) and exists as the first 2D ionic liquid up to 193 degrees C.
• Insight into the crystallization process: relationships between crystal structures and properties of copper(ii) coordination polymers containing dimethylbis(4-pyridyl)silane
  作者：So Yun Moon、Tae Hwan Noh、Ok-Sang Jung

  DOI：10.1039/c3ce40257f

  日期：——

  A systematic investigation into the favorable reaction conditions for construction of copper(II) coordination polymers was carried out. Various reactions of copper(II) bromide with dimethylbis(4-pyridyl)silane (L) produce two kinds of skeletal structures: the 1D loop-chain and the square-tubular helix. The fast-formation condition affords the 1D loop-chain, whereas the slow-formation condition yields the helical structure. The formation of significant condition-dependent structures can be partially attributed to the nature of the bromide anion and angle strain around the copper(II) cation. The relationships between structures and physicochemical properties such as anion exchangeability, catalytic oxidation of 3,5-di-tert-butylcatechol, and thermal properties are discussed in these pages.

  进行了一项系统研究，探讨构建铜(II)配位聚合物的有利反应条件。将铜(II)溴化物与二甲基双(4-吡啶基)硅烷(L)进行多种反应，生成了两种骨架结构：一维环链和方形螺旋管。快速形成的条件产生一维环链，而缓慢形成的条件产生螺旋结构。显著条件依赖性结构的形成可以部分归因于溴化物阴离子的性质以及铜(II)阳离子周围的角应变。本文讨论了这些结构与物理化学性质（如阴离子可交换性、3,5-二叔丁基邻苯二酚的催化氧化和热性质）之间的关系。